Catalytic activation of unstrained, non-activated ketones mediated by platinum(II) – multiple C–C bond cleavage and CO extrusion

Julia Paula Sarju; Debashish Dey; Javier Torroba; Adrian C. Whitwood; Kelly Robert Redeker; Duncan Watson Bruce

doi:10.1021/acs.organomet.9b00650

Catalytic activation of unstrained, non-activated ketones mediated by platinum(II) – multiple C–C bond cleavage and CO extrusion

Julia Paula Sarju, Debashish Dey, Javier Torroba, Adrian C. Whitwood, Kelly Robert Redeker, Duncan Watson Bruce

Research output: Contribution to journal › Article › peer-review

Abstract

The complexes [Pt(tolpy)Cl(L)] (tolpy = 2-(4-tolyl)pyridine; L = dmso, dms, py, PPh3, CO) are precursors for the catalytic cleavage of C–C bonds and extrusion of CO from a series of unactivated ketones such as cyclohexanone; deuterium labelling experiments demon-strate the involvement of a transfer hydrogen step in the mechanism

Original language	English
Number of pages	4
Journal	Organometallics
DOIs	https://doi.org/10.1021/acs.organomet.9b00650
Publication status	Published - 18 Nov 2019

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title = "Catalytic activation of unstrained, non-activated ketones mediated by platinum(II) – multiple C–C bond cleavage and CO extrusion",

abstract = "The complexes [Pt(tolpy)Cl(L)] (tolpy = 2-(4-tolyl)pyridine; L = dmso, dms, py, PPh3, CO) are precursors for the catalytic cleavage of C–C bonds and extrusion of CO from a series of unactivated ketones such as cyclohexanone; deuterium labelling experiments demon-strate the involvement of a transfer hydrogen step in the mechanism",

author = "Sarju, {Julia Paula} and Debashish Dey and Javier Torroba and Whitwood, {Adrian C.} and Redeker, {Kelly Robert} and Bruce, {Duncan Watson}",

year = "2019",

month = nov,

day = "18",

doi = "10.1021/acs.organomet.9b00650",

language = "English",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

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T1 - Catalytic activation of unstrained, non-activated ketones mediated by platinum(II) – multiple C–C bond cleavage and CO extrusion

AU - Sarju, Julia Paula

AU - Dey, Debashish

AU - Torroba, Javier

AU - Whitwood, Adrian C.

AU - Redeker, Kelly Robert

AU - Bruce, Duncan Watson

PY - 2019/11/18

Y1 - 2019/11/18

N2 - The complexes [Pt(tolpy)Cl(L)] (tolpy = 2-(4-tolyl)pyridine; L = dmso, dms, py, PPh3, CO) are precursors for the catalytic cleavage of C–C bonds and extrusion of CO from a series of unactivated ketones such as cyclohexanone; deuterium labelling experiments demon-strate the involvement of a transfer hydrogen step in the mechanism

AB - The complexes [Pt(tolpy)Cl(L)] (tolpy = 2-(4-tolyl)pyridine; L = dmso, dms, py, PPh3, CO) are precursors for the catalytic cleavage of C–C bonds and extrusion of CO from a series of unactivated ketones such as cyclohexanone; deuterium labelling experiments demon-strate the involvement of a transfer hydrogen step in the mechanism

U2 - 10.1021/acs.organomet.9b00650

DO - 10.1021/acs.organomet.9b00650

M3 - Article

SN - 0276-7333

JO - Organometallics

JF - Organometallics

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