Cationic phosphorus-carbon-pnictogen cages isolobal to [C5R5](+)

C  Fish; M  Green; J C  Jeffery; R J  Kilby; J M  Lynam; J E  McGrady; D A  Pantazis; C A  Russell; C E  Willans

doi:10.1039/b517710c

Cationic phosphorus-carbon-pnictogen cages isolobal to [C5R5](+)

C Fish, M Green, J C Jeffery, R J Kilby, J M Lynam, J E McGrady, D A Pantazis, C A Russell, C E Willans

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The cationic cages nido-[(C2Bu2P2E)-P-t](+) (E = As, Sb), which are isolobal to the cyclopentadienyl cation, adopt square based pyramidal structures with the heavy pnictogen atom at the apex; NMR and computational methods have been used to probe the dynamic behaviour of the complexes.

Original language	English
Pages (from-to)	1375-1377
Number of pages	3
Journal	Chemical Communications
Issue number	13
DOIs	https://doi.org/10.1039/b517710c
Publication status	Published - 2006

Keywords

SN(ETA(4)-P2C2BU2T)
DENSITY

Access to Document

10.1039/b517710c

Cite this

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title = "Cationic phosphorus-carbon-pnictogen cages isolobal to [C5R5](+)",

abstract = "The cationic cages nido-[(C2Bu2P2E)-P-t](+) (E = As, Sb), which are isolobal to the cyclopentadienyl cation, adopt square based pyramidal structures with the heavy pnictogen atom at the apex; NMR and computational methods have been used to probe the dynamic behaviour of the complexes.",

keywords = "SN(ETA(4)-P2C2BU2T), DENSITY",

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doi = "10.1039/b517710c",

language = "English",

pages = "1375--1377",

journal = "Chemical Communications",

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publisher = "The Royal Society of Chemistry",

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AU - Fish, C

AU - Green, M

AU - Jeffery, J C

AU - Kilby, R J

AU - Lynam, J M

AU - McGrady, J E

AU - Pantazis, D A

AU - Russell, C A

AU - Willans, C E

PY - 2006

Y1 - 2006

N2 - The cationic cages nido-[(C2Bu2P2E)-P-t](+) (E = As, Sb), which are isolobal to the cyclopentadienyl cation, adopt square based pyramidal structures with the heavy pnictogen atom at the apex; NMR and computational methods have been used to probe the dynamic behaviour of the complexes.

AB - The cationic cages nido-[(C2Bu2P2E)-P-t](+) (E = As, Sb), which are isolobal to the cyclopentadienyl cation, adopt square based pyramidal structures with the heavy pnictogen atom at the apex; NMR and computational methods have been used to probe the dynamic behaviour of the complexes.

KW - SN(ETA(4)-P2C2BU2T)

KW - DENSITY

U2 - 10.1039/b517710c

DO - 10.1039/b517710c

M3 - Article

SN - 1359-7345

SP - 1375

EP - 1377

JO - Chemical Communications

JF - Chemical Communications

IS - 13

ER -