CHARGE-TRANSFER INTERACTIONS BETWEEN SULFUR-DIOXIDE AND GROUP-8 HALF-SANDWICH COMPLEXES

C  HALL; J L  HARRIS; A  KILLEY; T P  MADDOX; S  PALMER; R N  PERUTZ; A D  ROONEY; S E J  GOFF; S G  KAZARIAN; M  POLIAKOFF

CHARGE-TRANSFER INTERACTIONS BETWEEN SULFUR-DIOXIDE AND GROUP-8 HALF-SANDWICH COMPLEXES

C HALL, J L HARRIS, A KILLEY, T P MADDOX, S PALMER, R N PERUTZ, A D ROONEY, S E J GOFF, S G KAZARIAN, M POLIAKOFF

Chemistry

Research output: Contribution to journal › Comment/debate › peer-review

Abstract

Mulliken-type charge-transfer complexes have been formed between basic half-sandwich compounds and SO2 when [M(eta(5)-C(5)R(5))(CO)(2)] (M = Rh or Ir; R(5) = Me(5), H-5 or H4CF3), [Ir(eta(5)-C5H5)(CO)(C2H4)], and [M(eta(5)-C5H5)(C2H4)(2)] (M = Co, Rh or Ir) are isolated in SO2-doped argon matrices at 20 K; the nu(CO) bands of the complexes are shifted to high frequency of those of the precursor molecules and prominent charge-transfer bands are observed; the same species have been detected when the compounds [M(eta(5)-C(5)Me(5))(CO)(2)] (M = Rh or Ir) are embedded in polyethylene discs and treated with SO2 at 213-298 K; the enthalpy of complexation of [Ir(eta(5)-C(5)Me(5))(CO)(2)] with SO2 is -13 +/- 3 kJ mol(-1).

Original language	English
Pages (from-to)	3515-3517
Number of pages	3
Journal	JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Issue number	23
Publication status	Published - 7 Dec 1994

Keywords

M = CO
ELECTRONIC-STRUCTURE
(ETA-5-C5ME5)IR(CO)2
ACTIVATION
IRIDIUM
LIGAND
RH

Cite this

@article{3b4dc623da6044c7a18bf9f0706ca2cb,

title = "CHARGE-TRANSFER INTERACTIONS BETWEEN SULFUR-DIOXIDE AND GROUP-8 HALF-SANDWICH COMPLEXES",

abstract = "Mulliken-type charge-transfer complexes have been formed between basic half-sandwich compounds and SO2 when [M(eta(5)-C(5)R(5))(CO)(2)] (M = Rh or Ir; R(5) = Me(5), H-5 or H4CF3), [Ir(eta(5)-C5H5)(CO)(C2H4)], and [M(eta(5)-C5H5)(C2H4)(2)] (M = Co, Rh or Ir) are isolated in SO2-doped argon matrices at 20 K; the nu(CO) bands of the complexes are shifted to high frequency of those of the precursor molecules and prominent charge-transfer bands are observed; the same species have been detected when the compounds [M(eta(5)-C(5)Me(5))(CO)(2)] (M = Rh or Ir) are embedded in polyethylene discs and treated with SO2 at 213-298 K; the enthalpy of complexation of [Ir(eta(5)-C(5)Me(5))(CO)(2)] with SO2 is -13 +/- 3 kJ mol(-1).",

keywords = "M = CO, ELECTRONIC-STRUCTURE, (ETA-5-C5ME5)IR(CO)2, ACTIVATION, IRIDIUM, LIGAND, RH",

author = "C HALL and HARRIS, {J L} and A KILLEY and MADDOX, {T P} and S PALMER and PERUTZ, {R N} and ROONEY, {A D} and GOFF, {S E J} and KAZARIAN, {S G} and M POLIAKOFF",

year = "1994",

month = dec,

day = "7",

language = "English",

pages = "3515--3517",

journal = "JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS",

issn = "1472-7773",

publisher = "The Royal Society of Chemistry",

number = "23",

}

TY - JOUR

T1 - CHARGE-TRANSFER INTERACTIONS BETWEEN SULFUR-DIOXIDE AND GROUP-8 HALF-SANDWICH COMPLEXES

AU - HALL, C

AU - HARRIS, J L

AU - KILLEY, A

AU - MADDOX, T P

AU - PALMER, S

AU - PERUTZ, R N

AU - ROONEY, A D

AU - GOFF, S E J

AU - KAZARIAN, S G

AU - POLIAKOFF, M

PY - 1994/12/7

Y1 - 1994/12/7

N2 - Mulliken-type charge-transfer complexes have been formed between basic half-sandwich compounds and SO2 when [M(eta(5)-C(5)R(5))(CO)(2)] (M = Rh or Ir; R(5) = Me(5), H-5 or H4CF3), [Ir(eta(5)-C5H5)(CO)(C2H4)], and [M(eta(5)-C5H5)(C2H4)(2)] (M = Co, Rh or Ir) are isolated in SO2-doped argon matrices at 20 K; the nu(CO) bands of the complexes are shifted to high frequency of those of the precursor molecules and prominent charge-transfer bands are observed; the same species have been detected when the compounds [M(eta(5)-C(5)Me(5))(CO)(2)] (M = Rh or Ir) are embedded in polyethylene discs and treated with SO2 at 213-298 K; the enthalpy of complexation of [Ir(eta(5)-C(5)Me(5))(CO)(2)] with SO2 is -13 +/- 3 kJ mol(-1).

AB - Mulliken-type charge-transfer complexes have been formed between basic half-sandwich compounds and SO2 when [M(eta(5)-C(5)R(5))(CO)(2)] (M = Rh or Ir; R(5) = Me(5), H-5 or H4CF3), [Ir(eta(5)-C5H5)(CO)(C2H4)], and [M(eta(5)-C5H5)(C2H4)(2)] (M = Co, Rh or Ir) are isolated in SO2-doped argon matrices at 20 K; the nu(CO) bands of the complexes are shifted to high frequency of those of the precursor molecules and prominent charge-transfer bands are observed; the same species have been detected when the compounds [M(eta(5)-C(5)Me(5))(CO)(2)] (M = Rh or Ir) are embedded in polyethylene discs and treated with SO2 at 213-298 K; the enthalpy of complexation of [Ir(eta(5)-C(5)Me(5))(CO)(2)] with SO2 is -13 +/- 3 kJ mol(-1).

KW - M = CO

KW - ELECTRONIC-STRUCTURE

KW - (ETA-5-C5ME5)IR(CO)2

KW - ACTIVATION

KW - IRIDIUM

KW - LIGAND

KW - RH

M3 - Comment/debate

SN - 1472-7773

SP - 3515

EP - 3517

JO - JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS

JF - JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS

IS - 23

ER -