Chemically modified mesoporous solids and their use in the polymerisation of hydrocarbon monomers

J H  Clark; K  Shorrock; V  Budarin; Karen Wilson

doi:10.1039/b107692m

Chemically modified mesoporous solids and their use in the polymerisation of hydrocarbon monomers

J H Clark, K Shorrock, V Budarin, Karen Wilson

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The controlled reaction of Lewis acids with mesoporous silica can be used to prepare solid cationic initiators useful for the polymerisation of hydrocarbons. These materials not only offer the advantage of enabling simpler processes and reduced waste but also show interesting and often dramatic differences from the behaviour of conventional homogenous cationic initiators due to solid surface and pore effects.

Original language	English
Pages (from-to)	423-427
Number of pages	5
Journal	JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Issue number	3
DOIs	https://doi.org/10.1039/b107692m
Publication status	Published - 2002

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10.1039/b107692m

Cite this

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title = "Chemically modified mesoporous solids and their use in the polymerisation of hydrocarbon monomers",

abstract = "The controlled reaction of Lewis acids with mesoporous silica can be used to prepare solid cationic initiators useful for the polymerisation of hydrocarbons. These materials not only offer the advantage of enabling simpler processes and reduced waste but also show interesting and often dramatic differences from the behaviour of conventional homogenous cationic initiators due to solid surface and pore effects.",

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AB - The controlled reaction of Lewis acids with mesoporous silica can be used to prepare solid cationic initiators useful for the polymerisation of hydrocarbons. These materials not only offer the advantage of enabling simpler processes and reduced waste but also show interesting and often dramatic differences from the behaviour of conventional homogenous cationic initiators due to solid surface and pore effects.

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DO - 10.1039/b107692m

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