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Chiral Ionic Liquid Crystals based on Thiourea

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JournalNEW JOURNAL OF CHEMISTRY
DateAccepted/In press - 10 Jan 2019
DateE-pub ahead of print - 10 Jan 2019
DatePublished (current) - 7 Feb 2019
Issue number5
Volume43
Number of pages4
Pages (from-to)2053-2056
Early online date10/01/19
Original languageEnglish

Abstract

Chiral ionic liquid crystals based on the S-methyl-N,N'-α-methylarylthiouronium cation have been prepared and studied. Most salts, interestingly including an example with the bistriflimide anion, display a SmA* phase with anion-dependent transition temperatures. The salts, which are able to distinguish enantiomers of chiral anions via formation of diastereomeric adducts, may find application as chiral reaction media.

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© The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2019. This is an author-produced version of the published paper. Uploaded in accordance with the publisher’s self-archiving policy. Further copying may not be permitted; contact the publisher for details.

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