CO2 photoreduction with long-wavelength light: dyads and monomers of zinc porphyrin and rhenium bipyridine

TY - JOUR

T1 - CO2 photoreduction with long-wavelength light

T2 - dyads and monomers of zinc porphyrin and rhenium bipyridine

AU - Windle, Christopher D.

AU - Campian, Marius V.

AU - Gibson, Elizabeth A.

AU - Perutz, Robin N.

AU - Schneider, Jacob

AU - Duhme-Klair, Anne

PY - 2012/8/25

Y1 - 2012/8/25

N2 - Photocatalytic CO2 reduction has been studied for two dyads with porphyrin covalently attached to rhenium tricarbonyl bipyridine moieties, and on separate components consisting of [Re(CO)(3)(Picoline)Bpy](+) and either zinc porphyrin or zinc chlorin. TONs decrease in the order: zinc porphyrin + Re > long spacer dyad > zinc chlorin + Re > short spacer dyad.

AB - Photocatalytic CO2 reduction has been studied for two dyads with porphyrin covalently attached to rhenium tricarbonyl bipyridine moieties, and on separate components consisting of [Re(CO)(3)(Picoline)Bpy](+) and either zinc porphyrin or zinc chlorin. TONs decrease in the order: zinc porphyrin + Re > long spacer dyad > zinc chlorin + Re > short spacer dyad.

UR - http://www.scopus.com/inward/record.url?scp=84864245941&partnerID=8YFLogxK

U2 - 10.1039/c2cc33308b

DO - 10.1039/c2cc33308b

M3 - Article

SN - 1359-7345

VL - 48

SP - 8189

EP - 8191

JO - Chemical Communications

JF - Chemical Communications

IS - 66

ER -