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CO2 photoreduction with long-wavelength light: dyads and monomers of zinc porphyrin and rhenium bipyridine
Research output: Contribution to journal › Article › peer-review
Published copy (DOI)
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Publication details
| Journal | Chemical Communications |
|---|---|
| Date | Published - 25 Aug 2012 |
| Issue number | 66 |
| Volume | 48 |
| Number of pages | 3 |
| Pages (from-to) | 8189-8191 |
| Original language | English |
Abstract
Photocatalytic CO2 reduction has been studied for two dyads with porphyrin covalently attached to rhenium tricarbonyl bipyridine moieties, and on separate components consisting of [Re(CO)(3)(Picoline)Bpy](+) and either zinc porphyrin or zinc chlorin. TONs decrease in the order: zinc porphyrin + Re > long spacer dyad > zinc chlorin + Re > short spacer dyad.
Projects
Carbon Dioxide & Alkanes as Electron-sink & Source
Project: Research project (funded) › Research
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