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CO2 photoreduction with long-wavelength light: dyads and monomers of zinc porphyrin and rhenium bipyridine

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JournalChemical Communications
DatePublished - 25 Aug 2012
Issue number66
Volume48
Number of pages3
Pages (from-to)8189-8191
Original languageEnglish

Abstract

Photocatalytic CO2 reduction has been studied for two dyads with porphyrin covalently attached to rhenium tricarbonyl bipyridine moieties, and on separate components consisting of [Re(CO)(3)(Picoline)Bpy](+) and either zinc porphyrin or zinc chlorin. TONs decrease in the order: zinc porphyrin + Re > long spacer dyad > zinc chlorin + Re > short spacer dyad.

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