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Cobalt-acetato complexes immobilised on PYPA-organomodified silica: a case study of different ways of immobilisation

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JournalJournal of Molecular Catalysis A: Chemical
DatePublished - 15 Mar 2004
Issue number1-2
Volume211
Number of pages9
Pages (from-to)209-217
Original languageEnglish

Abstract

In this paper, we compare the properties and activities of immobilised forms of in situ formed cobalt-acetato complexes of pyridin-4-ylmethyl-(3-triethoxysilanyl-propyl)-amine (PYPA) on organomodified hexagonal mesoporous silica (HMS) prepared via different routes, namely sol-gel synthesis, post-modification of sol-gel AMP-HMS, and grafting. All materials are able to act as host for cobalt-acetato complexes to different extents, and are able to catalyse the aerial oxidation of styrene. The support materials and catalysts were characterised by DRIFT, X-ray photoelectron spectroscopy (XPS), N-2 adsorption and elemental analysis, and compared with their homogeneous counterpart and a material obtained by grafting of a complex formed prior to immobilisation on the silica surface. (C) 2003 Elsevier B.V. All rights reserved.

    Research areas

  • supported catalysts, cobalt, oxidation, silica, MICELLE-TEMPLATED SILICA, SUPPORTED IMINES, BASE CATALYSTS, OXIDATION, ACIDS, HMS

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