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From the same journal

Concise asymmetric synthesis of (-)-sparteine

Research output: Contribution to journalArticle

Published copy (DOI)

Author(s)

  • J P R Hermet
  • M J McGrath
  • P O'Brien
  • D W Porter
  • J Gilday

Department/unit(s)

Publication details

JournalChemical Communications
DatePublished - 2004
Issue number16
Number of pages2
Pages (from-to)1830-1831
Original languageEnglish

Abstract

A six-step asymmetric synthesis of natural (-)-sparteine from ethyl 7-iodohept-2-enoate is reported, involving a connective Michael addition of an amino ester-derived enolate to an alpha,beta-unsaturated amino ester.

    Research areas

  • BETA-AMINO ESTERS, QUINOLIZIDINE ALKALOIDS, ACID-DERIVATIVES, CYCLIZATION REACTIONS, CONJUGATE ADDITION, MICHAEL ADDITION, LUPIN-ALKALOIDS, SPARTEINE, (+)-SPARTEINE

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