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Cooperation between catalytic sites on a bicipital supported phosphonium phase-transfer catalyst

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JournalChemical Communications
DatePublished - 7 Nov 1996
Issue number21
Number of pages2
Pages (from-to)2429-2430
Original languageEnglish

Abstract

A novel bicipital tetraarylphosphonium salt grafted to silica gel is prepared and characterised, and gives unusually high catalytic rate enhancements in some nucleophilic substitution reactions, which suggest cooperation between the neighbouring phosphonium centres.

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