Cyclisation of dienes using phosphorus-centred radicals to form organophosphorus adducts

C M  Jessop; A F  Parsons; A  Routledge; D  Irvine

Cyclisation of dienes using phosphorus-centred radicals to form organophosphorus adducts

C M Jessop, A F Parsons, A Routledge, D Irvine

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of various dienes with phosphites or related phosphorus hydrides, under free radical cyclisation conditions, affords cyclic organophosphorus adducts. This quick, mild and technically clean approach affords 5- and 6-ring carbocycles and heterocycles in good to excellent yield. (C) 2002 Elsevier Science Ltd. All rights reserved.

Original language	English
Pages (from-to)	479-483
Number of pages	5
Journal	Tetrahedron Letters
Volume	44
Issue number	3
Publication status	Published - 13 Jan 2003

Keywords

cyclisation
dienes
phosphorus compounds
radicals and radical reactions
CYCLIZATION REACTIONS
TRIBUTYLTIN HYDRIDE
PHOSPHINIC ACID
EFFICIENT
HETEROCYCLES
GENERATION
ALKENES
PHOSPHONOTHIOATES
REARRANGEMENT
HYPOPHOSPHITE

Cite this

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title = "Cyclisation of dienes using phosphorus-centred radicals to form organophosphorus adducts",

abstract = "Reaction of various dienes with phosphites or related phosphorus hydrides, under free radical cyclisation conditions, affords cyclic organophosphorus adducts. This quick, mild and technically clean approach affords 5- and 6-ring carbocycles and heterocycles in good to excellent yield. (C) 2002 Elsevier Science Ltd. All rights reserved.",

keywords = "cyclisation, dienes, phosphorus compounds, radicals and radical reactions, CYCLIZATION REACTIONS, TRIBUTYLTIN HYDRIDE, PHOSPHINIC ACID, EFFICIENT, HETEROCYCLES, GENERATION, ALKENES, PHOSPHONOTHIOATES, REARRANGEMENT, HYPOPHOSPHITE",

author = "Jessop, {C M} and Parsons, {A F} and A Routledge and D Irvine",

year = "2003",

month = jan,

day = "13",

language = "English",

volume = "44",

pages = "479--483",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier",

number = "3",

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TY - JOUR

T1 - Cyclisation of dienes using phosphorus-centred radicals to form organophosphorus adducts

AU - Jessop, C M

AU - Parsons, A F

AU - Routledge, A

AU - Irvine, D

PY - 2003/1/13

Y1 - 2003/1/13

N2 - Reaction of various dienes with phosphites or related phosphorus hydrides, under free radical cyclisation conditions, affords cyclic organophosphorus adducts. This quick, mild and technically clean approach affords 5- and 6-ring carbocycles and heterocycles in good to excellent yield. (C) 2002 Elsevier Science Ltd. All rights reserved.

AB - Reaction of various dienes with phosphites or related phosphorus hydrides, under free radical cyclisation conditions, affords cyclic organophosphorus adducts. This quick, mild and technically clean approach affords 5- and 6-ring carbocycles and heterocycles in good to excellent yield. (C) 2002 Elsevier Science Ltd. All rights reserved.

KW - cyclisation

KW - dienes

KW - phosphorus compounds

KW - radicals and radical reactions

KW - CYCLIZATION REACTIONS

KW - TRIBUTYLTIN HYDRIDE

KW - PHOSPHINIC ACID

KW - EFFICIENT

KW - HETEROCYCLES

KW - GENERATION

KW - ALKENES

KW - PHOSPHONOTHIOATES

KW - REARRANGEMENT

KW - HYPOPHOSPHITE

M3 - Article

VL - 44

SP - 479

EP - 483

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 3

ER -