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Cyclisation of dienes using phosphorus-centred radicals to form organophosphorus adducts

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JournalTetrahedron Letters
DatePublished - 13 Jan 2003
Issue number3
Volume44
Number of pages5
Pages (from-to)479-483
Original languageEnglish

Abstract

Reaction of various dienes with phosphites or related phosphorus hydrides, under free radical cyclisation conditions, affords cyclic organophosphorus adducts. This quick, mild and technically clean approach affords 5- and 6-ring carbocycles and heterocycles in good to excellent yield. (C) 2002 Elsevier Science Ltd. All rights reserved.

    Research areas

  • cyclisation, dienes, phosphorus compounds, radicals and radical reactions, CYCLIZATION REACTIONS, TRIBUTYLTIN HYDRIDE, PHOSPHINIC ACID, EFFICIENT, HETEROCYCLES, GENERATION, ALKENES, PHOSPHONOTHIOATES, REARRANGEMENT, HYPOPHOSPHITE

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