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Dearomative Cascade Photocatalysis: Divergent Synthesis through Catalyst Selective Energy Transfer

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Author(s)

  • Michael J. James
  • Jonas Luca Schwarz
  • Felix Strieth-Kalthoff
  • Birgit Wibbeling
  • Frank Glorius

Department/unit(s)

Publication details

JournalJournal of the American Chemical Society
DateAccepted/In press - 30 Jun 2018
DatePublished (current) - 1 Jul 2018
Issue number28
Volume140
Number of pages5
Pages (from-to)8624-8628
Original languageEnglish

Abstract

The discovery and application of dearomative cascade photocatalysis as a strategy in complex molecule synthesis is described. Visible-light-absorbing photosensitizers were used to (sequentially) activate a 1-naphthol derived arene precursor to divergently form two different polycyclic molecular scaffolds through catalyst selective energy transfer.

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© 2018 American Chemical Society. This is an author-produced version of the published paper. Uploaded in accordance with the publisher’s self-archiving policy. Further copying may not be permitted; contact the publisher for details.

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