Dendritic hydrogen bonding receptors: enantiomerically pure dendroclefts for the selective recognition of monosaccharides

D K  Smith; F  Diederich

Dendritic hydrogen bonding receptors: enantiomerically pure dendroclefts for the selective recognition of monosaccharides

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Enantiomerically pure dendritic cleft receptors (dendroclefts) with a 9,9'-spirobi[9H-fluorene] core are prepared for the recognition of glucopyranosides by I-I-bonding in CDCl3; the enantio- and diastereo-selectivities in the complexation processes are modulated by the presence of the dendritic shell.

Original language	English
Pages (from-to)	2501-2502
Number of pages	2
Journal	Chemical Communications
Issue number	22
Publication status	Published - 21 Nov 1998

Keywords

ENANTIOSELECTIVE COMPLEXATION
MOLECULAR RECOGNITION
DICARBOXYLIC-ACIDS
BORONIC ACID
BINDING
CLEFTS

Cite this

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title = "Dendritic hydrogen bonding receptors: enantiomerically pure dendroclefts for the selective recognition of monosaccharides",

abstract = "Enantiomerically pure dendritic cleft receptors (dendroclefts) with a 9,9'-spirobi[9H-fluorene] core are prepared for the recognition of glucopyranosides by I-I-bonding in CDCl3; the enantio- and diastereo-selectivities in the complexation processes are modulated by the presence of the dendritic shell.",

keywords = "ENANTIOSELECTIVE COMPLEXATION, MOLECULAR RECOGNITION, DICARBOXYLIC-ACIDS, BORONIC ACID, BINDING, CLEFTS",

author = "Smith, {D K} and F Diederich",

year = "1998",

month = nov,

day = "21",

language = "English",

pages = "2501--2502",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "The Royal Society of Chemistry",

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T1 - Dendritic hydrogen bonding receptors: enantiomerically pure dendroclefts for the selective recognition of monosaccharides

AU - Smith, D K

AU - Diederich, F

PY - 1998/11/21

Y1 - 1998/11/21

N2 - Enantiomerically pure dendritic cleft receptors (dendroclefts) with a 9,9'-spirobi[9H-fluorene] core are prepared for the recognition of glucopyranosides by I-I-bonding in CDCl3; the enantio- and diastereo-selectivities in the complexation processes are modulated by the presence of the dendritic shell.

AB - Enantiomerically pure dendritic cleft receptors (dendroclefts) with a 9,9'-spirobi[9H-fluorene] core are prepared for the recognition of glucopyranosides by I-I-bonding in CDCl3; the enantio- and diastereo-selectivities in the complexation processes are modulated by the presence of the dendritic shell.

KW - ENANTIOSELECTIVE COMPLEXATION

KW - MOLECULAR RECOGNITION

KW - DICARBOXYLIC-ACIDS

KW - BORONIC ACID

KW - BINDING

KW - CLEFTS

M3 - Article

SN - 1359-7345

SP - 2501

EP - 2502

JO - Chemical Communications

JF - Chemical Communications

IS - 22

ER -