By the same authors

From the same journal

Design of Neutral Metallomesogens from 5,5-Dimethyldipyrromethane: Metal Ion Mediated Control of Folding and Hairpin Structures

Research output: Contribution to journalLiterature review

Standard

Design of Neutral Metallomesogens from 5,5-Dimethyldipyrromethane: Metal Ion Mediated Control of Folding and Hairpin Structures. / Ames, Kelly A.; Collinson, Simon R.; Blake, Alexander J.; Wilson, Claire; Love, Jason B.; Bruce, Duncan W.; Donnio, Bertrand; Guillon, Daniel; Schroeder, Martin.

In: EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, No. 32, 11.2008, p. 5056-5066.

Research output: Contribution to journalLiterature review

Harvard

Ames, KA, Collinson, SR, Blake, AJ, Wilson, C, Love, JB, Bruce, DW, Donnio, B, Guillon, D & Schroeder, M 2008, 'Design of Neutral Metallomesogens from 5,5-Dimethyldipyrromethane: Metal Ion Mediated Control of Folding and Hairpin Structures', EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, no. 32, pp. 5056-5066. https://doi.org/10.1002/ejic.200800676

APA

Ames, K. A., Collinson, S. R., Blake, A. J., Wilson, C., Love, J. B., Bruce, D. W., ... Schroeder, M. (2008). Design of Neutral Metallomesogens from 5,5-Dimethyldipyrromethane: Metal Ion Mediated Control of Folding and Hairpin Structures. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, (32), 5056-5066. https://doi.org/10.1002/ejic.200800676

Vancouver

Ames KA, Collinson SR, Blake AJ, Wilson C, Love JB, Bruce DW et al. Design of Neutral Metallomesogens from 5,5-Dimethyldipyrromethane: Metal Ion Mediated Control of Folding and Hairpin Structures. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2008 Nov;(32):5056-5066. https://doi.org/10.1002/ejic.200800676

Author

Ames, Kelly A. ; Collinson, Simon R. ; Blake, Alexander J. ; Wilson, Claire ; Love, Jason B. ; Bruce, Duncan W. ; Donnio, Bertrand ; Guillon, Daniel ; Schroeder, Martin. / Design of Neutral Metallomesogens from 5,5-Dimethyldipyrromethane: Metal Ion Mediated Control of Folding and Hairpin Structures. In: EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2008 ; No. 32. pp. 5056-5066.

Bibtex - Download

@article{603c57c9a17543beb87c68abda389838,
title = "Design of Neutral Metallomesogens from 5,5-Dimethyldipyrromethane: Metal Ion Mediated Control of Folding and Hairpin Structures",
abstract = "New ligands derived from 5,5-dimethyldipyrromethane and their corresponding neutral complexes with Zn-II and Pd-II are described. The ligands incorporate either a hexacatenar [H2(1(n)), n = 1, 10, 12, 14 and 16], tetracatenar [H-2(2(n)), n = 1 and 16] or an extended dicatenar structure [H-2(3(n)), n = 1 and 16]. Single-crystal X-ray structure determinations of [Zn-2(1(1))(2)] and [Zn-2(3(1))(2)] confirm a distorted tetrahedral geometry at Zn-II to afford double-stranded helical structures, while the Pd-II species [Pd(3(1))] shows a distorted square-planar geometry with the ligand adopting an alternative hairpin conformation. The metal-free hexacatenar ligands H-2(1(n)) (n = 10, 12, 14, 16) and the corresponding complexes [Zn-2(1(16))(2)] and [Pd(1(n))] (n = 12, 14, 16) are not mesomorphic. However, the tetracatenar complex [Zn-2(2(16))(2)] generates a smectic mesophase, as confirmed by X-ray diffraction, while [Pd(2(16))] and the metal-free ligand H-2(2(16)) show no mesomorphic behaviour. Two of the extended dicatenar compounds, H-2(3(16)) and [Zn-2(3(16))(2)] are non-mesomorphic, while [Pd(3(16))] displays a smectic A phase. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)",
keywords = "Metallomesogens, Liquid crystals, Helical structures, Coordination chemistry, Supramolecular chemistry, Zinc, Palladium, Pyrromethane, Dipyrrolide, DISCOTIC LIQUID-CRYSTALS, SUPRAMOLECULAR CHEMISTRY, COLUMNAR MESOMORPHISM, PORPHYRIN OCTAESTERS, MOLECULAR-STRUCTURE, PHASE-BEHAVIOR, ALKOXY CHAINS, COMPLEXES, LIGANDS, MESOPHASES",
author = "Ames, {Kelly A.} and Collinson, {Simon R.} and Blake, {Alexander J.} and Claire Wilson and Love, {Jason B.} and Bruce, {Duncan W.} and Bertrand Donnio and Daniel Guillon and Martin Schroeder",
year = "2008",
month = "11",
doi = "10.1002/ejic.200800676",
language = "English",
pages = "5056--5066",
journal = "EUROPEAN JOURNAL OF INORGANIC CHEMISTRY",
issn = "1434-1948",
publisher = "Wiley-VCH Verlag",
number = "32",

}

RIS (suitable for import to EndNote) - Download

TY - JOUR

T1 - Design of Neutral Metallomesogens from 5,5-Dimethyldipyrromethane: Metal Ion Mediated Control of Folding and Hairpin Structures

AU - Ames, Kelly A.

AU - Collinson, Simon R.

AU - Blake, Alexander J.

AU - Wilson, Claire

AU - Love, Jason B.

AU - Bruce, Duncan W.

AU - Donnio, Bertrand

AU - Guillon, Daniel

AU - Schroeder, Martin

PY - 2008/11

Y1 - 2008/11

N2 - New ligands derived from 5,5-dimethyldipyrromethane and their corresponding neutral complexes with Zn-II and Pd-II are described. The ligands incorporate either a hexacatenar [H2(1(n)), n = 1, 10, 12, 14 and 16], tetracatenar [H-2(2(n)), n = 1 and 16] or an extended dicatenar structure [H-2(3(n)), n = 1 and 16]. Single-crystal X-ray structure determinations of [Zn-2(1(1))(2)] and [Zn-2(3(1))(2)] confirm a distorted tetrahedral geometry at Zn-II to afford double-stranded helical structures, while the Pd-II species [Pd(3(1))] shows a distorted square-planar geometry with the ligand adopting an alternative hairpin conformation. The metal-free hexacatenar ligands H-2(1(n)) (n = 10, 12, 14, 16) and the corresponding complexes [Zn-2(1(16))(2)] and [Pd(1(n))] (n = 12, 14, 16) are not mesomorphic. However, the tetracatenar complex [Zn-2(2(16))(2)] generates a smectic mesophase, as confirmed by X-ray diffraction, while [Pd(2(16))] and the metal-free ligand H-2(2(16)) show no mesomorphic behaviour. Two of the extended dicatenar compounds, H-2(3(16)) and [Zn-2(3(16))(2)] are non-mesomorphic, while [Pd(3(16))] displays a smectic A phase. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

AB - New ligands derived from 5,5-dimethyldipyrromethane and their corresponding neutral complexes with Zn-II and Pd-II are described. The ligands incorporate either a hexacatenar [H2(1(n)), n = 1, 10, 12, 14 and 16], tetracatenar [H-2(2(n)), n = 1 and 16] or an extended dicatenar structure [H-2(3(n)), n = 1 and 16]. Single-crystal X-ray structure determinations of [Zn-2(1(1))(2)] and [Zn-2(3(1))(2)] confirm a distorted tetrahedral geometry at Zn-II to afford double-stranded helical structures, while the Pd-II species [Pd(3(1))] shows a distorted square-planar geometry with the ligand adopting an alternative hairpin conformation. The metal-free hexacatenar ligands H-2(1(n)) (n = 10, 12, 14, 16) and the corresponding complexes [Zn-2(1(16))(2)] and [Pd(1(n))] (n = 12, 14, 16) are not mesomorphic. However, the tetracatenar complex [Zn-2(2(16))(2)] generates a smectic mesophase, as confirmed by X-ray diffraction, while [Pd(2(16))] and the metal-free ligand H-2(2(16)) show no mesomorphic behaviour. Two of the extended dicatenar compounds, H-2(3(16)) and [Zn-2(3(16))(2)] are non-mesomorphic, while [Pd(3(16))] displays a smectic A phase. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

KW - Metallomesogens

KW - Liquid crystals

KW - Helical structures

KW - Coordination chemistry

KW - Supramolecular chemistry

KW - Zinc

KW - Palladium

KW - Pyrromethane

KW - Dipyrrolide

KW - DISCOTIC LIQUID-CRYSTALS

KW - SUPRAMOLECULAR CHEMISTRY

KW - COLUMNAR MESOMORPHISM

KW - PORPHYRIN OCTAESTERS

KW - MOLECULAR-STRUCTURE

KW - PHASE-BEHAVIOR

KW - ALKOXY CHAINS

KW - COMPLEXES

KW - LIGANDS

KW - MESOPHASES

UR - http://www.scopus.com/inward/record.url?scp=56349158002&partnerID=8YFLogxK

U2 - 10.1002/ejic.200800676

DO - 10.1002/ejic.200800676

M3 - Literature review

SP - 5056

EP - 5066

JO - EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

JF - EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

SN - 1434-1948

IS - 32

ER -