Dimethylalkoxygallane incorporating a donor-functionalised alkoxide: The monomeric gas-phase structure

C.E. Knapp; C.J. Carmalt; P.F. McMillan; D.A. Wann; H.E. Robertson; D.W.H. Rankin

doi:10.1039/b817893n

Dimethylalkoxygallane incorporating a donor-functionalised alkoxide: The monomeric gas-phase structure

C.E. Knapp, C.J. Carmalt, P.F. McMillan, D.A. Wann, H.E. Robertson, D.W.H. Rankin

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The structure of the vapour produced upon heating the dimethylalkoxygallane [Me2GaOCH2CH2NMe2]2 has been studied by gas-phase electron diffraction and ab initio molecular orbital calculations; only the monomeric form [Me2GaOCH2CH 2NMe2] is observed in the vapour, with the nitrogen atom forming a dative bond with the metal centre. © 2008 The Royal Society of Chemistry.

Original language	Undefined/Unknown
Pages (from-to)	6880-6882
Number of pages	3
Journal	Dalton Transactions
Issue number	48
DOIs	https://doi.org/10.1039/b817893n
Publication status	Published - 2008

Bibliographical note

Cited By (since 1996):6

Export Date: 1 October 2013

Source: Scopus

doi: 10.1039/b817893n

PubMed ID: 19050772

Language of Original Document: English

Correspondence Address: Carmalt, C. J.; Materials Chemistry Centre, Department of Chemistry, University College London, 20 Gordon Street, London, WC1H 0AJ, United Kingdom; email: [email protected]

Chemicals/CAS: gallium, 7440-55-3; Alcohols; alkoxyl radical; Gallium, 7440-55-3; Gases; Organometallic Compounds

References: Jones, A.C., (2002) J. Mater. Chem., 12, p. 2576. , -2590; Jones, A.C., (1997) Chem. Soc. Rev., 26, p. 101. , -110; Carmalt, C.J., Basharat, S., Precursors to Semiconducting Materials (2007) Comprehensive Organometallic Chemistry III, , Elsevier Science Ltd., p. 1-34; Vernardou, D., Pemble, M.E., Sheel, D.W., (2008) Thin Solid Films, 516, p. 4502. , -4507; Holdsworth, R.J., Martin, P.A., Raisbeck, D., Rivero, J., Sanders, H.E., Sheel, D., Pemble, M.E., (2001) Chem. Vap. Deposition, 7, p. 39. , -43; Crosbie, M.J., Wright, P.J., Davies, H.O., Jones, A.C., Leedham, T.J., O'Brien, P., Critchlow, G.W., (1999) Chem. Vap. Deposition, 5, p. 9. , -12; Caulton, K.G., Hubert-Pfalzgraf, L.G., (1990) Chem. Rev., 90, p. 969. , -995; Bradley, D.C., (1994) Polyhedron, 13, p. 1111. , -1121; Mehrotra, R.C., Singh, A., Sogani, S., (1994) Chem. Rev., 94, p. 1643. , -1660; Chandler, C.D., Roger, C., Hampden-Smith, M.J., (1993) Chem. Rev., 93, p. 1205. , -1241; Veith, M., Mathur, S., Mathur, C., (1998) Polyhedron, 17, p. 1005. , -1034; Basharat, S., Carmalt, C.J., Binions, R., Palgrave, R., Parkin, I.P., (2008) Dalton Trans., p. 591. , -595; Basharat, S., Carmalt, C.J., King, S.J., Peters, E.S., Tocher, D.A., (2004) Dalton Trans., p. 3475. , -3480; Basharat, S., Carmalt, C.J., Palgrave, R., Barnett, S.A., Tocher, D.A., Davies, H.O., (2008) J. Organomet. Chem., 693, p. 1787. , -1796; Basharat, S., Carmalt, C.J., Barnett, S.A., Tocher, D.A., Davies, H.O., (2007) Inorg. Chem., 46, p. 9473. , -9480; Basharat, S., Knapp, C.E., Carmalt, C.J., Barnett, S., Tocher, D.A., (2008) New J. Chem., 32, p. 1513. , -1518; Basharat, S., Betchley, W., Carmalt, C.J., Barnett, S., Tocher, D.A., Davies, H.O., (2007) Organometallics, 26, p. 403. , -407; Carmalt, C.J., King, S.J., (2006) Coord. Chem. Rev., 250, p. 682. , and references therein -709; Binions, R., Carmalt, C.J., Parkin, I.P., Pratt, K.F.E., Shaw, G.A., (2004) Chem. Mater., 16, p. 2489. , -2493; Binions, R., Carmalt, C.J., Parkin, I.P., (2007) Meas. Sci. Technol., 18, p. 190. , -200; Hubert-Pfalzgraf, L.G., (1998) Coord. Chem. Rev., 178-180, p. 967. , -997; Rettig, S.J., Storr, A., Trotter, J., (1975) Can. J. Chem., 53, p. 58. , -66; Chi, Y., Chou, T.-Y., Wang, Y.-J., Huang, S.-F., Carty, A.J., Scoles, L., Udachin, K.A., Lee, G.-H., (2004) Organometallics, 23, p. 95. , -103

Keywords

Forming
Molecular orbitals
Ab Initio molecular orbital calculations
Alkoxide
Dative bonds
Metal centres
Monomeric forms
Monomeric gasses
Nitrogen atoms
Metal forming
alcohol derivative
alkoxy radical
gallium
organometallic compound
article
chemistry
gas
volatilization
Alcohols
Gallium
Gases
Organometallic Compounds
Volatilization

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Cite this

@article{dc1e7c810d4c41ebb5d57def598e87d9,

title = "Dimethylalkoxygallane incorporating a donor-functionalised alkoxide: The monomeric gas-phase structure",

abstract = "The structure of the vapour produced upon heating the dimethylalkoxygallane [Me2GaOCH2CH2NMe2]2 has been studied by gas-phase electron diffraction and ab initio molecular orbital calculations; only the monomeric form [Me2GaOCH2CH 2NMe2] is observed in the vapour, with the nitrogen atom forming a dative bond with the metal centre. {\textcopyright} 2008 The Royal Society of Chemistry.",

keywords = "Forming, Molecular orbitals, Ab Initio molecular orbital calculations, Alkoxide, Dative bonds, Metal centres, Monomeric forms, Monomeric gasses, Nitrogen atoms, Metal forming, alcohol derivative, alkoxy radical, gallium, organometallic compound, article, chemistry, gas, volatilization, Alcohols, Gallium, Gases, Organometallic Compounds, Volatilization",

author = "C.E. Knapp and C.J. Carmalt and P.F. McMillan and D.A. Wann and H.E. Robertson and D.W.H. Rankin",

note = "Cited By (since 1996):6 Export Date: 1 October 2013 Source: Scopus doi: 10.1039/b817893n PubMed ID: 19050772 Language of Original Document: English Correspondence Address: Carmalt, C. J.; Materials Chemistry Centre, Department of Chemistry, University College London, 20 Gordon Street, London, WC1H 0AJ, United Kingdom; email: [email protected] Chemicals/CAS: gallium, 7440-55-3; Alcohols; alkoxyl radical; Gallium, 7440-55-3; Gases; Organometallic Compounds References: Jones, A.C., (2002) J. Mater. Chem., 12, p. 2576. , -2590; Jones, A.C., (1997) Chem. Soc. Rev., 26, p. 101. , -110; Carmalt, C.J., Basharat, S., Precursors to Semiconducting Materials (2007) Comprehensive Organometallic Chemistry III, , Elsevier Science Ltd., p. 1-34; Vernardou, D., Pemble, M.E., Sheel, D.W., (2008) Thin Solid Films, 516, p. 4502. , -4507; Holdsworth, R.J., Martin, P.A., Raisbeck, D., Rivero, J., Sanders, H.E., Sheel, D., Pemble, M.E., (2001) Chem. Vap. Deposition, 7, p. 39. , -43; Crosbie, M.J., Wright, P.J., Davies, H.O., Jones, A.C., Leedham, T.J., O'Brien, P., Critchlow, G.W., (1999) Chem. Vap. Deposition, 5, p. 9. , -12; Caulton, K.G., Hubert-Pfalzgraf, L.G., (1990) Chem. Rev., 90, p. 969. , -995; Bradley, D.C., (1994) Polyhedron, 13, p. 1111. , -1121; Mehrotra, R.C., Singh, A., Sogani, S., (1994) Chem. Rev., 94, p. 1643. , -1660; Chandler, C.D., Roger, C., Hampden-Smith, M.J., (1993) Chem. Rev., 93, p. 1205. , -1241; Veith, M., Mathur, S., Mathur, C., (1998) Polyhedron, 17, p. 1005. , -1034; Basharat, S., Carmalt, C.J., Binions, R., Palgrave, R., Parkin, I.P., (2008) Dalton Trans., p. 591. , -595; Basharat, S., Carmalt, C.J., King, S.J., Peters, E.S., Tocher, D.A., (2004) Dalton Trans., p. 3475. , -3480; Basharat, S., Carmalt, C.J., Palgrave, R., Barnett, S.A., Tocher, D.A., Davies, H.O., (2008) J. Organomet. Chem., 693, p. 1787. , -1796; Basharat, S., Carmalt, C.J., Barnett, S.A., Tocher, D.A., Davies, H.O., (2007) Inorg. Chem., 46, p. 9473. , -9480; Basharat, S., Knapp, C.E., Carmalt, C.J., Barnett, S., Tocher, D.A., (2008) New J. Chem., 32, p. 1513. , -1518; Basharat, S., Betchley, W., Carmalt, C.J., Barnett, S., Tocher, D.A., Davies, H.O., (2007) Organometallics, 26, p. 403. , -407; Carmalt, C.J., King, S.J., (2006) Coord. Chem. Rev., 250, p. 682. , and references therein -709; Binions, R., Carmalt, C.J., Parkin, I.P., Pratt, K.F.E., Shaw, G.A., (2004) Chem. Mater., 16, p. 2489. , -2493; Binions, R., Carmalt, C.J., Parkin, I.P., (2007) Meas. Sci. Technol., 18, p. 190. , -200; Hubert-Pfalzgraf, L.G., (1998) Coord. Chem. Rev., 178-180, p. 967. , -997; Rettig, S.J., Storr, A., Trotter, J., (1975) Can. J. Chem., 53, p. 58. , -66; Chi, Y., Chou, T.-Y., Wang, Y.-J., Huang, S.-F., Carty, A.J., Scoles, L., Udachin, K.A., Lee, G.-H., (2004) Organometallics, 23, p. 95. , -103",

year = "2008",

doi = "10.1039/b817893n",

language = "Undefined/Unknown",

pages = "6880--6882",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "The Royal Society of Chemistry",

number = "48",

}

TY - JOUR

T1 - Dimethylalkoxygallane incorporating a donor-functionalised alkoxide: The monomeric gas-phase structure

AU - Knapp, C.E.

AU - Carmalt, C.J.

AU - McMillan, P.F.

AU - Wann, D.A.

AU - Robertson, H.E.

AU - Rankin, D.W.H.

N1 - Cited By (since 1996):6 Export Date: 1 October 2013 Source: Scopus doi: 10.1039/b817893n PubMed ID: 19050772 Language of Original Document: English Correspondence Address: Carmalt, C. J.; Materials Chemistry Centre, Department of Chemistry, University College London, 20 Gordon Street, London, WC1H 0AJ, United Kingdom; email: [email protected] Chemicals/CAS: gallium, 7440-55-3; Alcohols; alkoxyl radical; Gallium, 7440-55-3; Gases; Organometallic Compounds References: Jones, A.C., (2002) J. Mater. Chem., 12, p. 2576. , -2590; Jones, A.C., (1997) Chem. Soc. Rev., 26, p. 101. , -110; Carmalt, C.J., Basharat, S., Precursors to Semiconducting Materials (2007) Comprehensive Organometallic Chemistry III, , Elsevier Science Ltd., p. 1-34; Vernardou, D., Pemble, M.E., Sheel, D.W., (2008) Thin Solid Films, 516, p. 4502. , -4507; Holdsworth, R.J., Martin, P.A., Raisbeck, D., Rivero, J., Sanders, H.E., Sheel, D., Pemble, M.E., (2001) Chem. Vap. Deposition, 7, p. 39. , -43; Crosbie, M.J., Wright, P.J., Davies, H.O., Jones, A.C., Leedham, T.J., O'Brien, P., Critchlow, G.W., (1999) Chem. Vap. Deposition, 5, p. 9. , -12; Caulton, K.G., Hubert-Pfalzgraf, L.G., (1990) Chem. Rev., 90, p. 969. , -995; Bradley, D.C., (1994) Polyhedron, 13, p. 1111. , -1121; Mehrotra, R.C., Singh, A., Sogani, S., (1994) Chem. Rev., 94, p. 1643. , -1660; Chandler, C.D., Roger, C., Hampden-Smith, M.J., (1993) Chem. Rev., 93, p. 1205. , -1241; Veith, M., Mathur, S., Mathur, C., (1998) Polyhedron, 17, p. 1005. , -1034; Basharat, S., Carmalt, C.J., Binions, R., Palgrave, R., Parkin, I.P., (2008) Dalton Trans., p. 591. , -595; Basharat, S., Carmalt, C.J., King, S.J., Peters, E.S., Tocher, D.A., (2004) Dalton Trans., p. 3475. , -3480; Basharat, S., Carmalt, C.J., Palgrave, R., Barnett, S.A., Tocher, D.A., Davies, H.O., (2008) J. Organomet. Chem., 693, p. 1787. , -1796; Basharat, S., Carmalt, C.J., Barnett, S.A., Tocher, D.A., Davies, H.O., (2007) Inorg. Chem., 46, p. 9473. , -9480; Basharat, S., Knapp, C.E., Carmalt, C.J., Barnett, S., Tocher, D.A., (2008) New J. Chem., 32, p. 1513. , -1518; Basharat, S., Betchley, W., Carmalt, C.J., Barnett, S., Tocher, D.A., Davies, H.O., (2007) Organometallics, 26, p. 403. , -407; Carmalt, C.J., King, S.J., (2006) Coord. Chem. Rev., 250, p. 682. , and references therein -709; Binions, R., Carmalt, C.J., Parkin, I.P., Pratt, K.F.E., Shaw, G.A., (2004) Chem. Mater., 16, p. 2489. , -2493; Binions, R., Carmalt, C.J., Parkin, I.P., (2007) Meas. Sci. Technol., 18, p. 190. , -200; Hubert-Pfalzgraf, L.G., (1998) Coord. Chem. Rev., 178-180, p. 967. , -997; Rettig, S.J., Storr, A., Trotter, J., (1975) Can. J. Chem., 53, p. 58. , -66; Chi, Y., Chou, T.-Y., Wang, Y.-J., Huang, S.-F., Carty, A.J., Scoles, L., Udachin, K.A., Lee, G.-H., (2004) Organometallics, 23, p. 95. , -103

PY - 2008

Y1 - 2008

N2 - The structure of the vapour produced upon heating the dimethylalkoxygallane [Me2GaOCH2CH2NMe2]2 has been studied by gas-phase electron diffraction and ab initio molecular orbital calculations; only the monomeric form [Me2GaOCH2CH 2NMe2] is observed in the vapour, with the nitrogen atom forming a dative bond with the metal centre. © 2008 The Royal Society of Chemistry.

AB - The structure of the vapour produced upon heating the dimethylalkoxygallane [Me2GaOCH2CH2NMe2]2 has been studied by gas-phase electron diffraction and ab initio molecular orbital calculations; only the monomeric form [Me2GaOCH2CH 2NMe2] is observed in the vapour, with the nitrogen atom forming a dative bond with the metal centre. © 2008 The Royal Society of Chemistry.

KW - Forming

KW - Molecular orbitals

KW - Ab Initio molecular orbital calculations

KW - Alkoxide

KW - Dative bonds

KW - Metal centres

KW - Monomeric forms

KW - Monomeric gasses

KW - Nitrogen atoms

KW - Metal forming

KW - alcohol derivative

KW - alkoxy radical

KW - gallium

KW - organometallic compound

KW - article

KW - chemistry

KW - gas

KW - volatilization

KW - Alcohols

KW - Gallium

KW - Gases

KW - Organometallic Compounds

KW - Volatilization

U2 - 10.1039/b817893n

DO - 10.1039/b817893n

M3 - Article

SN - 1477-9226

SP - 6880

EP - 6882

JO - Dalton Transactions

JF - Dalton Transactions

IS - 48

ER -