Efficient conditions for the palladium(II) mediated coupling of organostannanes: The synthesis of 1,3-dienes, 1,4-dienes, 1,3-diynes and biphenyls

L  Alcaraz; R J K  Taylor

Efficient conditions for the palladium(II) mediated coupling of organostannanes: The synthesis of 1,3-dienes, 1,4-dienes, 1,3-diynes and biphenyls

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Convenient conditions are described for the preparation of 1,3-dienes by vinylstannane homocoupling using palladium(II)catalysis with oxygen (or air) for Pd(0)/Pd(II) reoxidation; related home-couplings, and cross-coupling reactions with allylstannane, are used to obtain 1,3-diynes, biaryls and 1,4-dienes.

Original language	English
Pages (from-to)	791
Number of pages	3
Journal	Synlett
Issue number	7
Publication status	Published - Jul 1997

Keywords

palladium coupling
organostannanes
1,3-dienes
1,4-dienes
1,3-diynes
biphenyls
ORGANOTIN COMPOUNDS
1-ALKENYLSTANNANES

Cite this

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title = "Efficient conditions for the palladium(II) mediated coupling of organostannanes: The synthesis of 1,3-dienes, 1,4-dienes, 1,3-diynes and biphenyls",

abstract = "Convenient conditions are described for the preparation of 1,3-dienes by vinylstannane homocoupling using palladium(II)catalysis with oxygen (or air) for Pd(0)/Pd(II) reoxidation; related home-couplings, and cross-coupling reactions with allylstannane, are used to obtain 1,3-diynes, biaryls and 1,4-dienes.",

keywords = "palladium coupling, organostannanes, 1,3-dienes, 1,4-dienes, 1,3-diynes, biphenyls, ORGANOTIN COMPOUNDS, 1-ALKENYLSTANNANES",

author = "L Alcaraz and Taylor, {R J K}",

year = "1997",

month = jul,

language = "English",

pages = "791",

journal = "Synlett",

issn = "1437-2096",

publisher = "Georg Thieme Verlag",

number = "7",

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TY - JOUR

T1 - Efficient conditions for the palladium(II) mediated coupling of organostannanes: The synthesis of 1,3-dienes, 1,4-dienes, 1,3-diynes and biphenyls

AU - Alcaraz, L

AU - Taylor, R J K

PY - 1997/7

Y1 - 1997/7

N2 - Convenient conditions are described for the preparation of 1,3-dienes by vinylstannane homocoupling using palladium(II)catalysis with oxygen (or air) for Pd(0)/Pd(II) reoxidation; related home-couplings, and cross-coupling reactions with allylstannane, are used to obtain 1,3-diynes, biaryls and 1,4-dienes.

AB - Convenient conditions are described for the preparation of 1,3-dienes by vinylstannane homocoupling using palladium(II)catalysis with oxygen (or air) for Pd(0)/Pd(II) reoxidation; related home-couplings, and cross-coupling reactions with allylstannane, are used to obtain 1,3-diynes, biaryls and 1,4-dienes.

KW - palladium coupling

KW - organostannanes

KW - 1,3-dienes

KW - 1,4-dienes

KW - 1,3-diynes

KW - biphenyls

KW - ORGANOTIN COMPOUNDS

KW - 1-ALKENYLSTANNANES

M3 - Article

SN - 1437-2096

SP - 791

JO - Synlett

JF - Synlett

IS - 7

ER -