Efficient radical coupling of organobromides using dimanganese decacarbonyl

B C  Gilbert; C I  Lindsay; P T  McGrail; A F  Parsons; D T E  Whittaker

Efficient radical coupling of organobromides using dimanganese decacarbonyl

B C Gilbert, C I Lindsay, P T McGrail, A F Parsons, D T E Whittaker

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Wurtz-type radical coupling of a variety of allylic and benzylic bromides was observed on irradiation with dimanganese decacarbonyl in excellent yield (77-99%). Efficient cross-coupling of two different bromides was also readily achieved.

Original language	English
Pages (from-to)	2711-2718
Number of pages	8
Journal	SYNTHETIC COMMUNICATIONS
Volume	29
Issue number	15
Publication status	Published - 1999

Keywords

ALKYL-HALIDES
ATOM TRANSFER
CYCLIZATION
COMPLEXES

Cite this

@article{f24338cb789445eb91f2e00dce4fb56f,

title = "Efficient radical coupling of organobromides using dimanganese decacarbonyl",

abstract = "Wurtz-type radical coupling of a variety of allylic and benzylic bromides was observed on irradiation with dimanganese decacarbonyl in excellent yield (77-99%). Efficient cross-coupling of two different bromides was also readily achieved.",

keywords = "ALKYL-HALIDES, ATOM TRANSFER, CYCLIZATION, COMPLEXES",

author = "Gilbert, {B C} and Lindsay, {C I} and McGrail, {P T} and Parsons, {A F} and Whittaker, {D T E}",

year = "1999",

language = "English",

volume = "29",

pages = "2711--2718",

journal = "SYNTHETIC COMMUNICATIONS",

issn = "0039-7911",

publisher = "Taylor & Francis",

number = "15",

}

TY - JOUR

T1 - Efficient radical coupling of organobromides using dimanganese decacarbonyl

AU - Gilbert, B C

AU - Lindsay, C I

AU - McGrail, P T

AU - Parsons, A F

AU - Whittaker, D T E

PY - 1999

Y1 - 1999

N2 - Wurtz-type radical coupling of a variety of allylic and benzylic bromides was observed on irradiation with dimanganese decacarbonyl in excellent yield (77-99%). Efficient cross-coupling of two different bromides was also readily achieved.

AB - Wurtz-type radical coupling of a variety of allylic and benzylic bromides was observed on irradiation with dimanganese decacarbonyl in excellent yield (77-99%). Efficient cross-coupling of two different bromides was also readily achieved.

KW - ALKYL-HALIDES

KW - ATOM TRANSFER

KW - CYCLIZATION

KW - COMPLEXES

M3 - Article

SN - 0039-7911

VL - 29

SP - 2711

EP - 2718

JO - SYNTHETIC COMMUNICATIONS

JF - SYNTHETIC COMMUNICATIONS

IS - 15

ER -