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Energy transfer catalysis mediated by visible light: principles, applications, directions

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JournalChemical Society Reviews
DateAccepted/In press - 8 Jul 2018
DatePublished (current) - 8 Aug 2018
Issue number19
Volume47
Number of pages13
Pages (from-to)7190-7202
Original languageEnglish

Abstract

Harnessing visible light to access excited (triplet) states of organic compounds can enable impressive reactivity modes. This tutorial review covers the photophysical fundamentals and most significant advances in the field of visible-light-mediated energy transfer catalysis within the last decade. Methods to determine excited triplet state energies and to characterize the underlying Dexter energy transfer are discussed. Synthetic applications of this field, divided into four main categories (cyclization reactions, double bond isomerizations, bond dissociations and sensitization of metal complexes), are also examined.

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© The Royal Society of Chemistry 2018. This is an author-produced version of the published paper. Uploaded in accordance with the publisher’s self-archiving policy. Further copying may not be permitted; contact the publisher for details.

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