EPISULFONE ALPHA-ANIONS - PREPARATION AND SYNTHETIC APPLICATIONS

A E  GRAHAM; W A  LOUGHLIN; R J K  TAYLOR

EPISULFONE ALPHA-ANIONS - PREPARATION AND SYNTHETIC APPLICATIONS

A E GRAHAM, W A LOUGHLIN, R J K TAYLOR

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Monosilyl-, monostannyl-, disilyl- and distannyl-episulfones have been prepared by episulfone alpha-anion generation followed by trapping with the appropriate electrophilic reagent. Elimination of sulfur dioxide provides a new route for the preparation of vinyl silanes and vinyl stannanes.

Original language	English
Pages (from-to)	7281-7284
Number of pages	4
Journal	Tetrahedron Letters
Volume	35
Issue number	39
Publication status	Published - 26 Sept 1994

Keywords

RAMBERG-BACKLUND REARRANGEMENT
SECONDARY REACTIONS
SULFONYL CHLORIDES
TERTIARY-AMINES
S,N-ADDUCTS
SULFENES
SILYL

Cite this

@article{e6fefae9d5f8400097555a3528a6912e,

title = "EPISULFONE ALPHA-ANIONS - PREPARATION AND SYNTHETIC APPLICATIONS",

abstract = "Monosilyl-, monostannyl-, disilyl- and distannyl-episulfones have been prepared by episulfone alpha-anion generation followed by trapping with the appropriate electrophilic reagent. Elimination of sulfur dioxide provides a new route for the preparation of vinyl silanes and vinyl stannanes.",

keywords = "RAMBERG-BACKLUND REARRANGEMENT, SECONDARY REACTIONS, SULFONYL CHLORIDES, TERTIARY-AMINES, S,N-ADDUCTS, SULFENES, SILYL",

author = "GRAHAM, {A E} and LOUGHLIN, {W A} and TAYLOR, {R J K}",

year = "1994",

month = sep,

day = "26",

language = "English",

volume = "35",

pages = "7281--7284",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier",

number = "39",

}

TY - JOUR

T1 - EPISULFONE ALPHA-ANIONS - PREPARATION AND SYNTHETIC APPLICATIONS

AU - GRAHAM, A E

AU - LOUGHLIN, W A

AU - TAYLOR, R J K

PY - 1994/9/26

Y1 - 1994/9/26

N2 - Monosilyl-, monostannyl-, disilyl- and distannyl-episulfones have been prepared by episulfone alpha-anion generation followed by trapping with the appropriate electrophilic reagent. Elimination of sulfur dioxide provides a new route for the preparation of vinyl silanes and vinyl stannanes.

AB - Monosilyl-, monostannyl-, disilyl- and distannyl-episulfones have been prepared by episulfone alpha-anion generation followed by trapping with the appropriate electrophilic reagent. Elimination of sulfur dioxide provides a new route for the preparation of vinyl silanes and vinyl stannanes.

KW - RAMBERG-BACKLUND REARRANGEMENT

KW - SECONDARY REACTIONS

KW - SULFONYL CHLORIDES

KW - TERTIARY-AMINES

KW - S,N-ADDUCTS

KW - SULFENES

KW - SILYL

M3 - Article

SN - 0040-4039

VL - 35

SP - 7281

EP - 7284

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 39

ER -