Evaluating the Local Bandgap Across inxGa1-xas Multiple Quantum Wells in a Metamorphic Laser via Low-Loss EELS

TY - JOUR

T1 - Evaluating the Local Bandgap Across inxGa1-xas Multiple Quantum Wells in a Metamorphic Laser via Low-Loss EELS

AU - Stephen, Nicholas

AU - Pinto-Huguet, Ivan

AU - Lawrence, Robert

AU - Kepaptsoglou, Demie

AU - Botifoll, Marc

AU - Gocalinska, Agnieszka

AU - Mura, Enrica

AU - Ramasse, Quentin

AU - Pelucchi, Emanuele

AU - Arbiol, Jordi

AU - Arredondo, Miryam

PY - 2025/4/4

Y1 - 2025/4/4

N2 - Abstract Using high-resolution scanning transmission electron microscopy and low-loss electron energy loss spectroscopy, the local bandgap (Eg), indium concentration, and strain distribution across multiple InxGa1-xAs quantum wells (QWs), on a GaAs substrate, within a metamorphic laser structure are correlated. The findings reveal significant inhomogeneities, particularly near the interfaces, for both the indium and strain distribution, and subtle variations in the Eg across individual QWs. The interplay between strain, composition, and Eg is further explored by density functional theory simulations, indicating that variations in the Eg are predominantly influenced by the indium concentration, with strain playing a minor role. The observed local inhomogeneities suggest that differences between individual QWs may affect the collective emission and performance of the final device. This study highlights the importance of spatially resolved analysis in understanding and optimizing the electronic and optical properties for designing next-generation metamorphic lasers with multiple QWs as the active region.

AB - Abstract Using high-resolution scanning transmission electron microscopy and low-loss electron energy loss spectroscopy, the local bandgap (Eg), indium concentration, and strain distribution across multiple InxGa1-xAs quantum wells (QWs), on a GaAs substrate, within a metamorphic laser structure are correlated. The findings reveal significant inhomogeneities, particularly near the interfaces, for both the indium and strain distribution, and subtle variations in the Eg across individual QWs. The interplay between strain, composition, and Eg is further explored by density functional theory simulations, indicating that variations in the Eg are predominantly influenced by the indium concentration, with strain playing a minor role. The observed local inhomogeneities suggest that differences between individual QWs may affect the collective emission and performance of the final device. This study highlights the importance of spatially resolved analysis in understanding and optimizing the electronic and optical properties for designing next-generation metamorphic lasers with multiple QWs as the active region.

KW - bandgap

KW - electron energy loss spectroscopy

KW - in concentration

KW - InGaAs

KW - quantum well

KW - strain distribution

U2 - 10.1002/admi.202400897

DO - 10.1002/admi.202400897

M3 - Article

SN - 2196-7350

VL - n/a

JO - Advanced materials interfaces

JF - Advanced materials interfaces

IS - n/a

M1 - 2400897

ER -