Evidence for the existence of Cu+ and Cu(CN)2 - in supported copper cyanide reagents

James H. Clark; Catherine V.A. Duke; Jack M. Miller; Stephen J. Brown

doi:10.1039/C39860000877

Evidence for the existence of Cu⁺ and Cu(CN)₂ ^- in supported copper cyanide reagents

James H. Clark^*, Catherine V.A. Duke, Jack M. Miller, Stephen J. Brown

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

I.r. analysis of supported CuCN reagents suggests that the active forms of these materials in nucleophilic cyanations contain the ions Cu⁺ and Cu(CN)₂^-; this is the first report of an active solid form of CuCN.

Original language	English
Pages (from-to)	877-878
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	11
DOIs	https://doi.org/10.1039/C39860000877
Publication status	Published - 1 Jan 1986

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10.1039/C39860000877

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@article{9135a8c8cdcf4f5f90f6c23a4c6055b7,

title = "Evidence for the existence of Cu+ and Cu(CN)2 - in supported copper cyanide reagents",

abstract = "I.r. analysis of supported CuCN reagents suggests that the active forms of these materials in nucleophilic cyanations contain the ions Cu+ and Cu(CN)2-; this is the first report of an active solid form of CuCN.",

author = "Clark, {James H.} and Duke, {Catherine V.A.} and Miller, {Jack M.} and Brown, {Stephen J.}",

year = "1986",

month = jan,

day = "1",

doi = "10.1039/C39860000877",

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journal = "Journal of the Chemical Society, Chemical Communications",

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T1 - Evidence for the existence of Cu+ and Cu(CN)2 - in supported copper cyanide reagents

AU - Clark, James H.

AU - Duke, Catherine V.A.

AU - Miller, Jack M.

AU - Brown, Stephen J.

PY - 1986/1/1

Y1 - 1986/1/1

N2 - I.r. analysis of supported CuCN reagents suggests that the active forms of these materials in nucleophilic cyanations contain the ions Cu+ and Cu(CN)2-; this is the first report of an active solid form of CuCN.

AB - I.r. analysis of supported CuCN reagents suggests that the active forms of these materials in nucleophilic cyanations contain the ions Cu+ and Cu(CN)2-; this is the first report of an active solid form of CuCN.

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U2 - 10.1039/C39860000877

DO - 10.1039/C39860000877

M3 - Article

SN - 0022-4936

SP - 877

EP - 878

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 11

ER -

Evidence for the existence of Cu+ and Cu(CN)2 - in supported copper cyanide reagents

Abstract

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Evidence for the existence of Cu⁺ and Cu(CN)₂ ^- in supported copper cyanide reagents