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exo-glycal approaches to C-linked glycosyl amino acid synthesis

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Publication details

JournalChemical Communications
DatePublished - 21 Aug 1999
Issue number16
Number of pages2
Pages (from-to)1599-1600
Original languageEnglish

Abstract

Two novel routes to C-linked glycosyl amino acids are described; the first involves elaboration of an exo-glycal and subsequent Ramberg-Backlund rearrangement of a sulfone intermediate to give, after functional group manipulation, a protected C-glycosyl serine, while the second uses hydroboration-Suzuki coupling of the same exo-glycal to produce ultimately the corresponding C-glycosyl asparagine analogue.

    Research areas

  • RAMBERG-BACKLUND REACTION, STEREOSELECTIVE SYNTHESIS, L-SERINE, ANALOG

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