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exo-glycal approaches to C-linked glycosyl amino acid synthesis
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Publication details
| Journal | Chemical Communications |
|---|---|
| Date | Published - 21 Aug 1999 |
| Issue number | 16 |
| Number of pages | 2 |
| Pages (from-to) | 1599-1600 |
| Original language | English |
Abstract
Two novel routes to C-linked glycosyl amino acids are described; the first involves elaboration of an exo-glycal and subsequent Ramberg-Backlund rearrangement of a sulfone intermediate to give, after functional group manipulation, a protected C-glycosyl serine, while the second uses hydroboration-Suzuki coupling of the same exo-glycal to produce ultimately the corresponding C-glycosyl asparagine analogue.
- RAMBERG-BACKLUND REACTION, STEREOSELECTIVE SYNTHESIS, L-SERINE, ANALOG
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