Facile, metal promoted, oxidation of eta(4)-1,3-diphosphacyclobutadiene by water or methanol: synthesis of [MoCl(CO)(eta(4)-1,3-P2C2Bu(t)(2))(eta(5)-L)] (L = C5H5, C5Me5) and [MoCl(CO){eta(3),lambda(3),lambda(5)-PC2Bu(t)(2)PH(OR)}(eta(5)-L)] (L = C5H5,R = H, Me)

A S  Weller; C D  Andrews; A D  Burrows; M  Green; J M  Lynam; M F  Mahon; C  Jones

Facile, metal promoted, oxidation of eta(4)-1,3-diphosphacyclobutadiene by water or methanol: synthesis of [MoCl(CO)(eta(4)-1,3-P2C2Bu(t)(2))(eta(5)-L)] (L = C5H5, C5Me5) and [MoCl(CO){eta(3),lambda(3),lambda(5)-PC2Bu(t)(2)PH(OR)}(eta(5)-L)] (L = C5H5,R = H, Me)

A S Weller, C D Andrews, A D Burrows, M Green, J M Lynam, M F Mahon, C Jones

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The new complexes [MoCl(CO)(eta(4)-1,3-P2C2Bu2t)(eta(5)-L)] (L = C5H5 1, C5Me5 2) are reported; facile oxidation of 1 with water or methanol affords a rare example of a mixed valence phosphaphosphonietinyl in [MoCl(CO){eta(3),lambda(3),lambda(5)-PC2Bu2t- PH(OR)}(eta(5)-C5H5)] (R = H, Me), which has also been structurally characterised for R=H.

Original language	English
Pages (from-to)	2147-2148
Number of pages	2
Journal	Chemical Communications
Issue number	21
Publication status	Published - 7 Nov 1999

Keywords

MOLECULAR-STRUCTURE
CRYSTAL-STRUCTURE
COMPLEX
PHOSPHAALKYNE
1,3-DIPHOSPHACYCLOBUTADIENE
CYCLODIMERIZATION
COORDINATION

Cite this

Weller, A. S., Andrews, C. D., Burrows, A. D., Green, M., Lynam, J. M., Mahon, M. F., & Jones, C. (1999). Facile, metal promoted, oxidation of eta(4)-1,3-diphosphacyclobutadiene by water or methanol: synthesis of [MoCl(CO)(eta(4)-1,3-P2C2Bu(t)(2))(eta(5)-L)] (L = C5H5, C5Me5) and [MoCl(CO){eta(3),lambda(3),lambda(5)-PC2Bu(t)(2)PH(OR)}(eta(5)-L)] (L = C5H5,R = H, Me). Chemical Communications, (21), 2147-2148.

Weller, A S ; Andrews, C D ; Burrows, A D et al. / Facile, metal promoted, oxidation of eta(4)-1,3-diphosphacyclobutadiene by water or methanol: synthesis of [MoCl(CO)(eta(4)-1,3-P2C2Bu(t)(2))(eta(5)-L)] (L = C5H5, C5Me5) and [MoCl(CO){eta(3),lambda(3),lambda(5)-PC2Bu(t)(2)PH(OR)}(eta(5)-L)] (L = C5H5,R = H, Me). In: Chemical Communications. 1999 ; No. 21. pp. 2147-2148.

@article{160603cfba66410891610a7d88044dd4,

title = "Facile, metal promoted, oxidation of eta(4)-1,3-diphosphacyclobutadiene by water or methanol: synthesis of [MoCl(CO)(eta(4)-1,3-P2C2Bu(t)(2))(eta(5)-L)] (L = C5H5, C5Me5) and [MoCl(CO){eta(3),lambda(3),lambda(5)-PC2Bu(t)(2)PH(OR)}(eta(5)-L)] (L = C5H5,R = H, Me)",

abstract = "The new complexes [MoCl(CO)(eta(4)-1,3-P2C2Bu2t)(eta(5)-L)] (L = C5H5 1, C5Me5 2) are reported; facile oxidation of 1 with water or methanol affords a rare example of a mixed valence phosphaphosphonietinyl in [MoCl(CO){eta(3),lambda(3),lambda(5)-PC2Bu2t- PH(OR)}(eta(5)-C5H5)] (R = H, Me), which has also been structurally characterised for R=H.",

keywords = "MOLECULAR-STRUCTURE, CRYSTAL-STRUCTURE, COMPLEX, PHOSPHAALKYNE, 1,3-DIPHOSPHACYCLOBUTADIENE, CYCLODIMERIZATION, COORDINATION",

author = "Weller, {A S} and Andrews, {C D} and Burrows, {A D} and M Green and Lynam, {J M} and Mahon, {M F} and C Jones",

year = "1999",

month = nov,

day = "7",

language = "English",

pages = "2147--2148",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "The Royal Society of Chemistry",

number = "21",

}

Weller, AS, Andrews, CD, Burrows, AD, Green, M, Lynam, JM, Mahon, MF & Jones, C 1999, 'Facile, metal promoted, oxidation of eta(4)-1,3-diphosphacyclobutadiene by water or methanol: synthesis of [MoCl(CO)(eta(4)-1,3-P2C2Bu(t)(2))(eta(5)-L)] (L = C5H5, C5Me5) and [MoCl(CO){eta(3),lambda(3),lambda(5)-PC2Bu(t)(2)PH(OR)}(eta(5)-L)] (L = C5H5,R = H, Me)', Chemical Communications, no. 21, pp. 2147-2148.

Facile, metal promoted, oxidation of eta(4)-1,3-diphosphacyclobutadiene by water or methanol: synthesis of [MoCl(CO)(eta(4)-1,3-P2C2Bu(t)(2))(eta(5)-L)] (L = C5H5, C5Me5) and [MoCl(CO){eta(3),lambda(3),lambda(5)-PC2Bu(t)(2)PH(OR)}(eta(5)-L)] (L = C5H5,R = H, Me). / Weller, A S ; Andrews, C D ; Burrows, A D et al.
In: Chemical Communications, No. 21, 07.11.1999, p. 2147-2148.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Facile, metal promoted, oxidation of eta(4)-1,3-diphosphacyclobutadiene by water or methanol: synthesis of [MoCl(CO)(eta(4)-1,3-P2C2Bu(t)(2))(eta(5)-L)] (L = C5H5, C5Me5) and [MoCl(CO){eta(3),lambda(3),lambda(5)-PC2Bu(t)(2)PH(OR)}(eta(5)-L)] (L = C5H5,R = H, Me)

AU - Weller, A S

AU - Andrews, C D

AU - Burrows, A D

AU - Green, M

AU - Lynam, J M

AU - Mahon, M F

AU - Jones, C

PY - 1999/11/7

Y1 - 1999/11/7

N2 - The new complexes [MoCl(CO)(eta(4)-1,3-P2C2Bu2t)(eta(5)-L)] (L = C5H5 1, C5Me5 2) are reported; facile oxidation of 1 with water or methanol affords a rare example of a mixed valence phosphaphosphonietinyl in [MoCl(CO){eta(3),lambda(3),lambda(5)-PC2Bu2t- PH(OR)}(eta(5)-C5H5)] (R = H, Me), which has also been structurally characterised for R=H.

AB - The new complexes [MoCl(CO)(eta(4)-1,3-P2C2Bu2t)(eta(5)-L)] (L = C5H5 1, C5Me5 2) are reported; facile oxidation of 1 with water or methanol affords a rare example of a mixed valence phosphaphosphonietinyl in [MoCl(CO){eta(3),lambda(3),lambda(5)-PC2Bu2t- PH(OR)}(eta(5)-C5H5)] (R = H, Me), which has also been structurally characterised for R=H.

KW - MOLECULAR-STRUCTURE

KW - CRYSTAL-STRUCTURE

KW - COMPLEX

KW - PHOSPHAALKYNE

KW - 1,3-DIPHOSPHACYCLOBUTADIENE

KW - CYCLODIMERIZATION

KW - COORDINATION

M3 - Article

SN - 1359-7345

SP - 2147

EP - 2148

JO - Chemical Communications

JF - Chemical Communications

IS - 21

ER -

Weller AS, Andrews CD, Burrows AD, Green M, Lynam JM, Mahon MF et al. Facile, metal promoted, oxidation of eta(4)-1,3-diphosphacyclobutadiene by water or methanol: synthesis of [MoCl(CO)(eta(4)-1,3-P2C2Bu(t)(2))(eta(5)-L)] (L = C5H5, C5Me5) and [MoCl(CO){eta(3),lambda(3),lambda(5)-PC2Bu(t)(2)PH(OR)}(eta(5)-L)] (L = C5H5,R = H, Me). Chemical Communications. 1999 Nov 7;(21):2147-2148.