Formation of a hetero[3]rotaxane by a dynamic component-swapping strategy

Eleanor A Wilson; Nicolaas A Vermeulen; Paul R McGonigal; Alyssa-Jennifer Avestro; Amy A Sarjeant; Charlotte L Stern; J Fraser Stoddart

doi:10.1039/c4cc03612c

Formation of a hetero[3]rotaxane by a dynamic component-swapping strategy

Eleanor A Wilson, Nicolaas A Vermeulen, Paul R McGonigal, Alyssa-Jennifer Avestro, Amy A Sarjeant, Charlotte L Stern, J Fraser Stoddart

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Acid-catalysed scrambling of the mechanically interlocked components between two different homo[3]rotaxanes, constituted of dumbbells containing two secondary dialkylammonium ion recognition sites encircled by two [24]crown-8 rings, each containing a couple of imine bonds, affords a statistical mixture of a hetero[3]rotaxane along with the two homo[3]rotaxanes, indicating that neither selectivity nor cooperativity is operating during the assembly process.

Original language	English
Pages (from-to)	9665-9668
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	68
DOIs	https://doi.org/10.1039/c4cc03612c
Publication status	Published - 4 Sept 2014

Access to Document

10.1039/c4cc03612c

Cite this

@article{7ef8a64741994668a7676ff7c7b1e95f,

title = "Formation of a hetero[3]rotaxane by a dynamic component-swapping strategy",

abstract = "Acid-catalysed scrambling of the mechanically interlocked components between two different homo[3]rotaxanes, constituted of dumbbells containing two secondary dialkylammonium ion recognition sites encircled by two [24]crown-8 rings, each containing a couple of imine bonds, affords a statistical mixture of a hetero[3]rotaxane along with the two homo[3]rotaxanes, indicating that neither selectivity nor cooperativity is operating during the assembly process. ",

author = "Wilson, {Eleanor A} and Vermeulen, {Nicolaas A} and McGonigal, {Paul R} and Alyssa-Jennifer Avestro and Sarjeant, {Amy A} and Stern, {Charlotte L} and Stoddart, {J Fraser}",

year = "2014",

month = sep,

day = "4",

doi = "10.1039/c4cc03612c",

language = "English",

volume = "50",

pages = "9665--9668",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "The Royal Society of Chemistry",

number = "68",

}

TY - JOUR

T1 - Formation of a hetero[3]rotaxane by a dynamic component-swapping strategy

AU - Wilson, Eleanor A

AU - Vermeulen, Nicolaas A

AU - McGonigal, Paul R

AU - Avestro, Alyssa-Jennifer

AU - Sarjeant, Amy A

AU - Stern, Charlotte L

AU - Stoddart, J Fraser

PY - 2014/9/4

Y1 - 2014/9/4

N2 - Acid-catalysed scrambling of the mechanically interlocked components between two different homo[3]rotaxanes, constituted of dumbbells containing two secondary dialkylammonium ion recognition sites encircled by two [24]crown-8 rings, each containing a couple of imine bonds, affords a statistical mixture of a hetero[3]rotaxane along with the two homo[3]rotaxanes, indicating that neither selectivity nor cooperativity is operating during the assembly process.

AB - Acid-catalysed scrambling of the mechanically interlocked components between two different homo[3]rotaxanes, constituted of dumbbells containing two secondary dialkylammonium ion recognition sites encircled by two [24]crown-8 rings, each containing a couple of imine bonds, affords a statistical mixture of a hetero[3]rotaxane along with the two homo[3]rotaxanes, indicating that neither selectivity nor cooperativity is operating during the assembly process.

U2 - 10.1039/c4cc03612c

DO - 10.1039/c4cc03612c

M3 - Article

C2 - 25019588

SN - 1359-7345

VL - 50

SP - 9665

EP - 9668

JO - Chemical Communications

JF - Chemical Communications

IS - 68

ER -