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Formation of a hetero[3]rotaxane by a dynamic component-swapping strategy

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Published copy (DOI)

Author(s)

  • Eleanor A Wilson
  • Nicolaas A Vermeulen
  • Paul R McGonigal
  • Alyssa-Jennifer Avestro
  • Amy A Sarjeant
  • Charlotte L Stern
  • J Fraser Stoddart

Department/unit(s)

Publication details

JournalChemical Communications
DatePublished - 4 Sep 2014
Issue number68
Volume50
Number of pages4
Pages (from-to)9665-8
Original languageEnglish

Abstract

Acid-catalysed scrambling of the mechanically interlocked components between two different homo[3]rotaxanes, constituted of dumbbells containing two secondary dialkylammonium ion recognition sites encircled by two [24]crown-8 rings, each containing a couple of imine bonds, affords a statistical mixture of a hetero[3]rotaxane along with the two homo[3]rotaxanes, indicating that neither selectivity nor cooperativity is operating during the assembly process.

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