Formation of fluoro-meisenheimer complexes using homogeneous and heterogeneous fluoride ion sources

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Research output: Contribution to journal › Article

Published copy (DOI)

10.1016/S0022-1139(00)81139-2

Author(s)

J. H. Clark
M. S. Robertson
D. K. Smith
A. Cook
C. Streich

Department/unit(s)

Publication details

Journal	JOURNAL OF FLUORINE CHEMISTRY
Date	Published - 1 Jan 1985
Issue number	2
Volume	28
Number of pages	9
Pages (from-to)	161-169
Original language	English

Abstract

1-Chloro-2,4-dinitrobenzene, 1-fluoro-2,4-dinitrobenzene and 1,3-dinitrobenzene form Meisenheimer complexes with tetra-n-butylammonium fluoride and alumina supported alkali metal fluorides. Both kinetically controlled and thermodynamically controlled complexes are observed.

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