Fourier transform emission spectroscopy of a new (2)Phi-1(2) Delta system of VO

R S  Ram; P F  Bernath; S P  Davis; A J  Merer

doi:10.1006/jmsp.2001.8510

Fourier transform emission spectroscopy of a new (2)Phi-1(2) Delta system of VO

R S Ram, P F Bernath, S P Davis, A J Merer

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

High-resolution emission spectra of VO have been recorded in the region 3400-19400 cm(-1) using a Fourier transform spectrometer. The molecules were observed from the reaction of VOCl3 with active nitrogen. Two new bands, with origins near 5539.46 and 5551.69 cm(-1), are assigned as the 0-0 bands of the (2)Phi(5/2)-(2)Delta(3/2) and (2)Phi(7/2)-(2)Delta(5/2) spin-orbit components (respectively) of a (2)Phi-1(2)Delta electronic transition of VO. A rotational analysis of both subbands has been carried out and spectroscopic constants have been extracted. The 1(2)Delta state is known from the previous analysis of the near infrared doublet transitions of VO and the new (2)Phi excited state has rotational constants very similar to those of another (2)Phi state observed previously [Merer et al., J. Mol. Spectrosc. 125, 465 (1987)]. (C) 2002 Elsevier Science (USA).

Original language	English
Pages (from-to)	279-283
Number of pages	5
Journal	JOURNAL OF MOLECULAR SPECTROSCOPY
Volume	211
Issue number	2
DOIs	https://doi.org/10.1006/jmsp.2001.8510
Publication status	Published - Feb 2002

Keywords

ROTATIONAL STRUCTURE
SPECTRA
STATES
PERTURBATIONS
TRANSITION
OXIDES
BAND

Access to Document

10.1006/jmsp.2001.8510

Cite this

@article{f46bddc13a884787b8e303576ffdcefc,

title = "Fourier transform emission spectroscopy of a new (2)Phi-1(2) Delta system of VO",

abstract = "High-resolution emission spectra of VO have been recorded in the region 3400-19400 cm(-1) using a Fourier transform spectrometer. The molecules were observed from the reaction of VOCl3 with active nitrogen. Two new bands, with origins near 5539.46 and 5551.69 cm(-1), are assigned as the 0-0 bands of the (2)Phi(5/2)-(2)Delta(3/2) and (2)Phi(7/2)-(2)Delta(5/2) spin-orbit components (respectively) of a (2)Phi-1(2)Delta electronic transition of VO. A rotational analysis of both subbands has been carried out and spectroscopic constants have been extracted. The 1(2)Delta state is known from the previous analysis of the near infrared doublet transitions of VO and the new (2)Phi excited state has rotational constants very similar to those of another (2)Phi state observed previously [Merer et al., J. Mol. Spectrosc. 125, 465 (1987)]. (C) 2002 Elsevier Science (USA).",

keywords = "ROTATIONAL STRUCTURE, SPECTRA, STATES, PERTURBATIONS, TRANSITION, OXIDES, BAND",

author = "Ram, {R S} and Bernath, {P F} and Davis, {S P} and Merer, {A J}",

year = "2002",

month = feb,

doi = "10.1006/jmsp.2001.8510",

language = "English",

volume = "211",

pages = "279--283",

journal = "JOURNAL OF MOLECULAR SPECTROSCOPY",

issn = "0022-2852",

publisher = "Academic Press",

number = "2",

}

TY - JOUR

T1 - Fourier transform emission spectroscopy of a new (2)Phi-1(2) Delta system of VO

AU - Ram, R S

AU - Bernath, P F

AU - Davis, S P

AU - Merer, A J

PY - 2002/2

Y1 - 2002/2

N2 - High-resolution emission spectra of VO have been recorded in the region 3400-19400 cm(-1) using a Fourier transform spectrometer. The molecules were observed from the reaction of VOCl3 with active nitrogen. Two new bands, with origins near 5539.46 and 5551.69 cm(-1), are assigned as the 0-0 bands of the (2)Phi(5/2)-(2)Delta(3/2) and (2)Phi(7/2)-(2)Delta(5/2) spin-orbit components (respectively) of a (2)Phi-1(2)Delta electronic transition of VO. A rotational analysis of both subbands has been carried out and spectroscopic constants have been extracted. The 1(2)Delta state is known from the previous analysis of the near infrared doublet transitions of VO and the new (2)Phi excited state has rotational constants very similar to those of another (2)Phi state observed previously [Merer et al., J. Mol. Spectrosc. 125, 465 (1987)]. (C) 2002 Elsevier Science (USA).

AB - High-resolution emission spectra of VO have been recorded in the region 3400-19400 cm(-1) using a Fourier transform spectrometer. The molecules were observed from the reaction of VOCl3 with active nitrogen. Two new bands, with origins near 5539.46 and 5551.69 cm(-1), are assigned as the 0-0 bands of the (2)Phi(5/2)-(2)Delta(3/2) and (2)Phi(7/2)-(2)Delta(5/2) spin-orbit components (respectively) of a (2)Phi-1(2)Delta electronic transition of VO. A rotational analysis of both subbands has been carried out and spectroscopic constants have been extracted. The 1(2)Delta state is known from the previous analysis of the near infrared doublet transitions of VO and the new (2)Phi excited state has rotational constants very similar to those of another (2)Phi state observed previously [Merer et al., J. Mol. Spectrosc. 125, 465 (1987)]. (C) 2002 Elsevier Science (USA).

KW - ROTATIONAL STRUCTURE

KW - SPECTRA

KW - STATES

KW - PERTURBATIONS

KW - TRANSITION

KW - OXIDES

KW - BAND

U2 - 10.1006/jmsp.2001.8510

DO - 10.1006/jmsp.2001.8510

M3 - Article

SN - 0022-2852

VL - 211

SP - 279

EP - 283

JO - JOURNAL OF MOLECULAR SPECTROSCOPY

JF - JOURNAL OF MOLECULAR SPECTROSCOPY

IS - 2

ER -