Fourier transform emission spectroscopy of some new bands of ReN

R. S. Ram; P. F. Bernath; W. J. Balfour

doi:10.1016/j.jms.2007.09.013

Fourier transform emission spectroscopy of some new bands of ReN

R. S. Ram, P. F. Bernath, W. J. Balfour

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The emission spectrum of ReN has been reinvestigated in the visible region using a Fourier transform spectrometer. Two new bands have been identified with band origins near 22110 and 22224 cm(-1). These bands have a common lower state and have been assigned as the 0(+)-A1 and 0(-)-A1 transitions. After rotational analysis it was noted that the new 0(+)-A1 transition also has its upper state in common with the upper state of the [24.7]0(+)-X0(+) transition reported previously [W.J. Balfour, J. Cao, CXW. Qian, S.J. Rixon, J. Mol. Spectrosc. 18 3 (1997) 113-118.]. This observation provides T-oo = 2616.26 cm(-1) for the A1 state. It is likely that the A1 and XO+ states are two spin components of the (3)Sigma(-) ground state. (c) 2007 Elsevier Inc. All rights reserved.

Original language	English
Pages (from-to)	192-197
Number of pages	6
Journal	JOURNAL OF MOLECULAR SPECTROSCOPY
Volume	246
Issue number	2
DOIs	https://doi.org/10.1016/j.jms.2007.09.013
Publication status	Published - Dec 2007

Keywords

Fourier transform spectroscopy
high resolution electronic spectroscopy
diatomic transition metal nitrides
LASER
SYSTEM

Access to Document

10.1016/j.jms.2007.09.013

Cite this

@article{9d0655b64dcd44e880111b40e854a06e,

title = "Fourier transform emission spectroscopy of some new bands of ReN",

abstract = "The emission spectrum of ReN has been reinvestigated in the visible region using a Fourier transform spectrometer. Two new bands have been identified with band origins near 22110 and 22224 cm(-1). These bands have a common lower state and have been assigned as the 0(+)-A1 and 0(-)-A1 transitions. After rotational analysis it was noted that the new 0(+)-A1 transition also has its upper state in common with the upper state of the [24.7]0(+)-X0(+) transition reported previously [W.J. Balfour, J. Cao, CXW. Qian, S.J. Rixon, J. Mol. Spectrosc. 18 3 (1997) 113-118.]. This observation provides T-oo = 2616.26 cm(-1) for the A1 state. It is likely that the A1 and XO+ states are two spin components of the (3)Sigma(-) ground state. (c) 2007 Elsevier Inc. All rights reserved.",

keywords = "Fourier transform spectroscopy, high resolution electronic spectroscopy, diatomic transition metal nitrides, LASER, SYSTEM",

author = "Ram, {R. S.} and Bernath, {P. F.} and Balfour, {W. J.}",

year = "2007",

month = dec,

doi = "10.1016/j.jms.2007.09.013",

language = "English",

volume = "246",

pages = "192--197",

journal = "JOURNAL OF MOLECULAR SPECTROSCOPY",

issn = "0022-2852",

publisher = "Academic Press",

number = "2",

}

TY - JOUR

T1 - Fourier transform emission spectroscopy of some new bands of ReN

AU - Ram, R. S.

AU - Bernath, P. F.

AU - Balfour, W. J.

PY - 2007/12

Y1 - 2007/12

N2 - The emission spectrum of ReN has been reinvestigated in the visible region using a Fourier transform spectrometer. Two new bands have been identified with band origins near 22110 and 22224 cm(-1). These bands have a common lower state and have been assigned as the 0(+)-A1 and 0(-)-A1 transitions. After rotational analysis it was noted that the new 0(+)-A1 transition also has its upper state in common with the upper state of the [24.7]0(+)-X0(+) transition reported previously [W.J. Balfour, J. Cao, CXW. Qian, S.J. Rixon, J. Mol. Spectrosc. 18 3 (1997) 113-118.]. This observation provides T-oo = 2616.26 cm(-1) for the A1 state. It is likely that the A1 and XO+ states are two spin components of the (3)Sigma(-) ground state. (c) 2007 Elsevier Inc. All rights reserved.

AB - The emission spectrum of ReN has been reinvestigated in the visible region using a Fourier transform spectrometer. Two new bands have been identified with band origins near 22110 and 22224 cm(-1). These bands have a common lower state and have been assigned as the 0(+)-A1 and 0(-)-A1 transitions. After rotational analysis it was noted that the new 0(+)-A1 transition also has its upper state in common with the upper state of the [24.7]0(+)-X0(+) transition reported previously [W.J. Balfour, J. Cao, CXW. Qian, S.J. Rixon, J. Mol. Spectrosc. 18 3 (1997) 113-118.]. This observation provides T-oo = 2616.26 cm(-1) for the A1 state. It is likely that the A1 and XO+ states are two spin components of the (3)Sigma(-) ground state. (c) 2007 Elsevier Inc. All rights reserved.

KW - Fourier transform spectroscopy

KW - high resolution electronic spectroscopy

KW - diatomic transition metal nitrides

KW - LASER

KW - SYSTEM

U2 - 10.1016/j.jms.2007.09.013

DO - 10.1016/j.jms.2007.09.013

M3 - Article

VL - 246

SP - 192

EP - 197

JO - JOURNAL OF MOLECULAR SPECTROSCOPY

JF - JOURNAL OF MOLECULAR SPECTROSCOPY

SN - 0022-2852

IS - 2

ER -