Fourier transform emission spectroscopy of the A(2)Delta-Chi(2)Pi transition of SiH and SiD

R S  Ram; R  Engleman; P F  Bernath

Fourier transform emission spectroscopy of the A(2)Delta-Chi(2)Pi transition of SiH and SiD

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The emission spectra of the A(2)Delta-(XII)-I-2 transition of SiH and SiD have been observed at high resolution using a Fourier transform spectrometer. The molecules were excited in a Si hollow cathode lamp by passing a discharge through a mixture of Ne and a trace of H-2 or D-2. The present data, combined with the previous infrared vibration-rotation measurements, have been used to determine improved molecular constants for the ground and excited states of Sill and SID. (C) 1998 Academic Press.

Original language	English
Pages (from-to)	341-352
Number of pages	12
Journal	JOURNAL OF MOLECULAR SPECTROSCOPY
Volume	190
Issue number	2
Publication status	Published - Aug 1998

Keywords

LASER MAGNETIC-RESONANCE
SILANE GLOW-DISCHARGE
THEORETICAL ENTHALPIES
ABINITIO CALCULATIONS
VIBRATION-ROTATION
DIATOMIC-MOLECULES
INFRARED-SPECTRUM
PLASMA DEPOSITION
GROUND-STATE
RADICALS

Cite this

@article{f588d12961c94e1f9b59c482b55e761b,

title = "Fourier transform emission spectroscopy of the A(2)Delta-Chi(2)Pi transition of SiH and SiD",

abstract = "The emission spectra of the A(2)Delta-(XII)-I-2 transition of SiH and SiD have been observed at high resolution using a Fourier transform spectrometer. The molecules were excited in a Si hollow cathode lamp by passing a discharge through a mixture of Ne and a trace of H-2 or D-2. The present data, combined with the previous infrared vibration-rotation measurements, have been used to determine improved molecular constants for the ground and excited states of Sill and SID. (C) 1998 Academic Press.",

keywords = "LASER MAGNETIC-RESONANCE, SILANE GLOW-DISCHARGE, THEORETICAL ENTHALPIES, ABINITIO CALCULATIONS, VIBRATION-ROTATION, DIATOMIC-MOLECULES, INFRARED-SPECTRUM, PLASMA DEPOSITION, GROUND-STATE, RADICALS",

author = "Ram, {R S} and R Engleman and Bernath, {P F}",

year = "1998",

month = aug,

language = "English",

volume = "190",

pages = "341--352",

journal = "JOURNAL OF MOLECULAR SPECTROSCOPY",

issn = "0022-2852",

publisher = "Academic Press",

number = "2",

}

TY - JOUR

T1 - Fourier transform emission spectroscopy of the A(2)Delta-Chi(2)Pi transition of SiH and SiD

AU - Ram, R S

AU - Engleman, R

AU - Bernath, P F

PY - 1998/8

Y1 - 1998/8

N2 - The emission spectra of the A(2)Delta-(XII)-I-2 transition of SiH and SiD have been observed at high resolution using a Fourier transform spectrometer. The molecules were excited in a Si hollow cathode lamp by passing a discharge through a mixture of Ne and a trace of H-2 or D-2. The present data, combined with the previous infrared vibration-rotation measurements, have been used to determine improved molecular constants for the ground and excited states of Sill and SID. (C) 1998 Academic Press.

AB - The emission spectra of the A(2)Delta-(XII)-I-2 transition of SiH and SiD have been observed at high resolution using a Fourier transform spectrometer. The molecules were excited in a Si hollow cathode lamp by passing a discharge through a mixture of Ne and a trace of H-2 or D-2. The present data, combined with the previous infrared vibration-rotation measurements, have been used to determine improved molecular constants for the ground and excited states of Sill and SID. (C) 1998 Academic Press.

KW - LASER MAGNETIC-RESONANCE

KW - SILANE GLOW-DISCHARGE

KW - THEORETICAL ENTHALPIES

KW - ABINITIO CALCULATIONS

KW - VIBRATION-ROTATION

KW - DIATOMIC-MOLECULES

KW - INFRARED-SPECTRUM

KW - PLASMA DEPOSITION

KW - GROUND-STATE

KW - RADICALS

M3 - Article

SN - 0022-2852

VL - 190

SP - 341

EP - 352

JO - JOURNAL OF MOLECULAR SPECTROSCOPY

JF - JOURNAL OF MOLECULAR SPECTROSCOPY

IS - 2

ER -