Fourier transform emission spectroscopy of the E                    Π-X                     Σ                     transition of CaH and CaD

R.S. Ram; K. Tereszchuk; P.F. Bernath; I.E. Gordon; K.A. Walker

doi:10.1016/j.jms.2011.03.009

Fourier transform emission spectroscopy of the E Π-X Σ transition of CaH and CaD

R.S. Ram, K. Tereszchuk, P.F. Bernath, I.E. Gordon, K.A. Walker

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The emission spectra of CaH and CaD have been recorded at high resolution using a Fourier transform spectrometer and bands belonging to the E Π-X Σ transition have been measured in the 20 100-20 700 cm region. A rotational analysis of 0-0 and 1-1 bands of both the isotopologues has been carried out. The present measurements have been combined with the previously available pure rotation and vibration-rotation data to provide improved spectroscopic constants for the E Π state. The constants ΔG() = 1199.8867(34) cm , B = 4.345032(49) cm , α = 0.122115(92) cm , r = 1.986633(11) for CaH, and ΔG()=868.7438(46) cm , B = 2.212496(51) cm , α = 0.036509(97) cm , r = 1.993396(23) for CaD have been determined.

Original language	English
Pages (from-to)	86-91
Number of pages	6
Journal	JOURNAL OF MOLECULAR SPECTROSCOPY
Volume	266
Issue number	2
DOIs	https://doi.org/10.1016/j.jms.2011.03.009
Publication status	Published - 1 Apr 2011

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@article{2c1684d024304395a7a4243d235d56e2,

title = "Fourier transform emission spectroscopy of the E Π-X Σ transition of CaH and CaD",

abstract = "The emission spectra of CaH and CaD have been recorded at high resolution using a Fourier transform spectrometer and bands belonging to the E Π-X Σ transition have been measured in the 20 100-20 700 cm region. A rotational analysis of 0-0 and 1-1 bands of both the isotopologues has been carried out. The present measurements have been combined with the previously available pure rotation and vibration-rotation data to provide improved spectroscopic constants for the E Π state. The constants ΔG() = 1199.8867(34) cm , B = 4.345032(49) cm , α = 0.122115(92) cm , r = 1.986633(11) for CaH, and ΔG()=868.7438(46) cm , B = 2.212496(51) cm , α = 0.036509(97) cm , r = 1.993396(23) for CaD have been determined.",

author = "R.S. Ram and K. Tereszchuk and P.F. Bernath and I.E. Gordon and K.A. Walker",

year = "2011",

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day = "1",

doi = "10.1016/j.jms.2011.03.009",

language = "English",

volume = "266",

pages = "86--91",

journal = "JOURNAL OF MOLECULAR SPECTROSCOPY",

issn = "0022-2852",

publisher = "Academic Press",

number = "2",

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TY - JOUR

T1 - Fourier transform emission spectroscopy of the E Π-X Σ transition of CaH and CaD

AU - Ram, R.S.

AU - Tereszchuk, K.

AU - Bernath, P.F.

AU - Gordon, I.E.

AU - Walker, K.A.

PY - 2011/4/1

Y1 - 2011/4/1

N2 - The emission spectra of CaH and CaD have been recorded at high resolution using a Fourier transform spectrometer and bands belonging to the E Π-X Σ transition have been measured in the 20 100-20 700 cm region. A rotational analysis of 0-0 and 1-1 bands of both the isotopologues has been carried out. The present measurements have been combined with the previously available pure rotation and vibration-rotation data to provide improved spectroscopic constants for the E Π state. The constants ΔG() = 1199.8867(34) cm , B = 4.345032(49) cm , α = 0.122115(92) cm , r = 1.986633(11) for CaH, and ΔG()=868.7438(46) cm , B = 2.212496(51) cm , α = 0.036509(97) cm , r = 1.993396(23) for CaD have been determined.

AB - The emission spectra of CaH and CaD have been recorded at high resolution using a Fourier transform spectrometer and bands belonging to the E Π-X Σ transition have been measured in the 20 100-20 700 cm region. A rotational analysis of 0-0 and 1-1 bands of both the isotopologues has been carried out. The present measurements have been combined with the previously available pure rotation and vibration-rotation data to provide improved spectroscopic constants for the E Π state. The constants ΔG() = 1199.8867(34) cm , B = 4.345032(49) cm , α = 0.122115(92) cm , r = 1.986633(11) for CaH, and ΔG()=868.7438(46) cm , B = 2.212496(51) cm , α = 0.036509(97) cm , r = 1.993396(23) for CaD have been determined.

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U2 - 10.1016/j.jms.2011.03.009

DO - 10.1016/j.jms.2011.03.009

M3 - Article

AN - SCOPUS:79955923158

SN - 0022-2852

VL - 266

SP - 86

EP - 91

JO - JOURNAL OF MOLECULAR SPECTROSCOPY

JF - JOURNAL OF MOLECULAR SPECTROSCOPY

IS - 2

ER -

Fourier transform emission spectroscopy of the E Π-X Σ transition of CaH and CaD

Abstract

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