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From Siderophores and Self-Assembly to Luminescent Sensors: The Binding of Molybdenum by Catecholamides

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From Siderophores and Self-Assembly to Luminescent Sensors: The Binding of Molybdenum by Catecholamides. / Duhme-Klair, Anne-K.

In: EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, No. 25, 09.2009, p. 3689-3701.

Research output: Contribution to journalLiterature review

Harvard

Duhme-Klair, A-K 2009, 'From Siderophores and Self-Assembly to Luminescent Sensors: The Binding of Molybdenum by Catecholamides', EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, no. 25, pp. 3689-3701. https://doi.org/10.1002/ejic.200900416

APA

Duhme-Klair, A-K. (2009). From Siderophores and Self-Assembly to Luminescent Sensors: The Binding of Molybdenum by Catecholamides. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, (25), 3689-3701. https://doi.org/10.1002/ejic.200900416

Vancouver

Duhme-Klair A-K. From Siderophores and Self-Assembly to Luminescent Sensors: The Binding of Molybdenum by Catecholamides. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2009 Sep;(25):3689-3701. https://doi.org/10.1002/ejic.200900416

Author

Duhme-Klair, Anne-K. / From Siderophores and Self-Assembly to Luminescent Sensors: The Binding of Molybdenum by Catecholamides. In: EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2009 ; No. 25. pp. 3689-3701.

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@article{afddd47694194572a1a4d12e5c4dfa56,
title = "From Siderophores and Self-Assembly to Luminescent Sensors: The Binding of Molybdenum by Catecholamides",
abstract = "Molybdate reacts readily and instantly with 2,3-dihydroxy-benzamide-containing ligands (catecholamides) to give stable cis-dioxido-Mo-VI complexes. This reaction is of biological relevance, because it results in the competition of molybdate with Fe-III for siderophores of the catecholamide type. These siderophores are secreted by bacteria to acquire essential Fe-III and help the cells to cope with variations in metal ion concentrations in their environment. This microreview summarises the insights obtained in this area and analyses the structures of the Mo-VI complexes formed. In addition, the scope of the structure-defining potential of the cis-dioxido-Mo-VI unit in the self-assembly of supramolecular structures is illustrated. The final part of the review describes how catecholamide units can be used in the development of luminescent chemosensors for molybdate. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)",
keywords = "Molybdenum, Siderophores, Self-assembly, Bioinorganic chemistry, Luminescent sensors, TRANSITION-METAL-COMPLEXES, MLCT EXCITED-STATES, AZOTOBACTER-VINELANDII, SPECTROFLUOROMETRIC DETERMINATION, SPECTROSCOPIC PROPERTIES, CRYSTAL-STRUCTURE, BRIDGING LIGAND, CIS-DIOXOMOLYBDENUM(VI) COMPLEX, COORDINATION CHEMISTRY, MOLYBDATE TRANSPORT",
author = "Anne-K. Duhme-Klair",
year = "2009",
month = "9",
doi = "10.1002/ejic.200900416",
language = "English",
pages = "3689--3701",
journal = "EUROPEAN JOURNAL OF INORGANIC CHEMISTRY",
issn = "1434-1948",
publisher = "Wiley-VCH Verlag",
number = "25",

}

RIS (suitable for import to EndNote) - Download

TY - JOUR

T1 - From Siderophores and Self-Assembly to Luminescent Sensors: The Binding of Molybdenum by Catecholamides

AU - Duhme-Klair, Anne-K.

PY - 2009/9

Y1 - 2009/9

N2 - Molybdate reacts readily and instantly with 2,3-dihydroxy-benzamide-containing ligands (catecholamides) to give stable cis-dioxido-Mo-VI complexes. This reaction is of biological relevance, because it results in the competition of molybdate with Fe-III for siderophores of the catecholamide type. These siderophores are secreted by bacteria to acquire essential Fe-III and help the cells to cope with variations in metal ion concentrations in their environment. This microreview summarises the insights obtained in this area and analyses the structures of the Mo-VI complexes formed. In addition, the scope of the structure-defining potential of the cis-dioxido-Mo-VI unit in the self-assembly of supramolecular structures is illustrated. The final part of the review describes how catecholamide units can be used in the development of luminescent chemosensors for molybdate. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

AB - Molybdate reacts readily and instantly with 2,3-dihydroxy-benzamide-containing ligands (catecholamides) to give stable cis-dioxido-Mo-VI complexes. This reaction is of biological relevance, because it results in the competition of molybdate with Fe-III for siderophores of the catecholamide type. These siderophores are secreted by bacteria to acquire essential Fe-III and help the cells to cope with variations in metal ion concentrations in their environment. This microreview summarises the insights obtained in this area and analyses the structures of the Mo-VI complexes formed. In addition, the scope of the structure-defining potential of the cis-dioxido-Mo-VI unit in the self-assembly of supramolecular structures is illustrated. The final part of the review describes how catecholamide units can be used in the development of luminescent chemosensors for molybdate. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

KW - Molybdenum

KW - Siderophores

KW - Self-assembly

KW - Bioinorganic chemistry

KW - Luminescent sensors

KW - TRANSITION-METAL-COMPLEXES

KW - MLCT EXCITED-STATES

KW - AZOTOBACTER-VINELANDII

KW - SPECTROFLUOROMETRIC DETERMINATION

KW - SPECTROSCOPIC PROPERTIES

KW - CRYSTAL-STRUCTURE

KW - BRIDGING LIGAND

KW - CIS-DIOXOMOLYBDENUM(VI) COMPLEX

KW - COORDINATION CHEMISTRY

KW - MOLYBDATE TRANSPORT

UR - http://www.scopus.com/inward/record.url?scp=69049109813&partnerID=8YFLogxK

U2 - 10.1002/ejic.200900416

DO - 10.1002/ejic.200900416

M3 - Literature review

SP - 3689

EP - 3701

JO - EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

JF - EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

SN - 1434-1948

IS - 25

ER -