GAS-PHASE INORGANIC-CHEMISTRY - LASER SPECTROSCOPY OF CALCIUM AND STRONTIUM MONOTHIOLATES AND MONOHYDROSULFIDES

W T M L  FERNANDO; R S  RAM; L C  OBRIEN; P F  BERNATH

GAS-PHASE INORGANIC-CHEMISTRY - LASER SPECTROSCOPY OF CALCIUM AND STRONTIUM MONOTHIOLATES AND MONOHYDROSULFIDES

W T M L FERNANDO, R S RAM, L C OBRIEN, P F BERNATH

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The gas-phase reaction of Ca and Sr vapors with various thiols and hydrogen sulfide was studied. These reactions produced the metal monothiolates CaSR and SrSR, where R = H, CH3, CH2CH3, etc. Three electronic transitions, C2A' - X2A', B2A" - X2A', and A2A' - X2A', were detected by laser-induced fluorescence. The spectra are consistent with a bent Ca-S-R structure. Some Ca-S and Sr-S stretching frequencies were determined from the spectra.

Original language	English
Pages (from-to)	2665-2668
Number of pages	4
Journal	Journal of Physical Chemistry A
Volume	95
Issue number	7
Publication status	Published - 4 Apr 1991

Keywords

FREE-RADICALS
TRANSITION
SYSTEM
SROH

Cite this

@article{446f907cc2674c46b8cb87b089956785,

title = "GAS-PHASE INORGANIC-CHEMISTRY - LASER SPECTROSCOPY OF CALCIUM AND STRONTIUM MONOTHIOLATES AND MONOHYDROSULFIDES",

abstract = "The gas-phase reaction of Ca and Sr vapors with various thiols and hydrogen sulfide was studied. These reactions produced the metal monothiolates CaSR and SrSR, where R = H, CH3, CH2CH3, etc. Three electronic transitions, C2A' - X2A', B2A{"} - X2A', and A2A' - X2A', were detected by laser-induced fluorescence. The spectra are consistent with a bent Ca-S-R structure. Some Ca-S and Sr-S stretching frequencies were determined from the spectra.",

keywords = "FREE-RADICALS, TRANSITION, SYSTEM, SROH",

author = "FERNANDO, {W T M L} and RAM, {R S} and OBRIEN, {L C} and BERNATH, {P F}",

year = "1991",

month = apr,

day = "4",

language = "English",

volume = "95",

pages = "2665--2668",

journal = "Journal of Physical Chemistry A",

issn = "1089-5639",

publisher = "American Chemical Society",

number = "7",

}

TY - JOUR

T1 - GAS-PHASE INORGANIC-CHEMISTRY - LASER SPECTROSCOPY OF CALCIUM AND STRONTIUM MONOTHIOLATES AND MONOHYDROSULFIDES

AU - FERNANDO, W T M L

AU - RAM, R S

AU - OBRIEN, L C

AU - BERNATH, P F

PY - 1991/4/4

Y1 - 1991/4/4

N2 - The gas-phase reaction of Ca and Sr vapors with various thiols and hydrogen sulfide was studied. These reactions produced the metal monothiolates CaSR and SrSR, where R = H, CH3, CH2CH3, etc. Three electronic transitions, C2A' - X2A', B2A" - X2A', and A2A' - X2A', were detected by laser-induced fluorescence. The spectra are consistent with a bent Ca-S-R structure. Some Ca-S and Sr-S stretching frequencies were determined from the spectra.

AB - The gas-phase reaction of Ca and Sr vapors with various thiols and hydrogen sulfide was studied. These reactions produced the metal monothiolates CaSR and SrSR, where R = H, CH3, CH2CH3, etc. Three electronic transitions, C2A' - X2A', B2A" - X2A', and A2A' - X2A', were detected by laser-induced fluorescence. The spectra are consistent with a bent Ca-S-R structure. Some Ca-S and Sr-S stretching frequencies were determined from the spectra.

KW - FREE-RADICALS

KW - TRANSITION

KW - SYSTEM

KW - SROH

M3 - Article

SN - 1089-5639

VL - 95

SP - 2665

EP - 2668

JO - Journal of Physical Chemistry A

JF - Journal of Physical Chemistry A

IS - 7

ER -