GAS-PHASE INORGANIC-CHEMISTRY - MONOVALENT DERIVATIVES OF CALCIUM AND STRONTIUM

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Abstract

The chemistry and spectroscopy of monovalent derivatives of calcium and strontium are described. Laser-driven chemical reactions of calcium and strontium vapors with a variety of small molecules have provided many new free radicals. In general, these species are analogous to the stable molecules obtained in traditional inorganic or organometallic chemistry, but some new families of molecules have been discovered.

Original languageEnglish
Pages (from-to)665-670
Number of pages6
JournalScience
Volume254
Issue number5032
Publication statusPublished - 1 Nov 1991

Keywords

  • RESOLUTION LASER SPECTROSCOPY
  • ELECTRON PROPAGATOR CALCULATIONS
  • ALKALINE-EARTH MONOHYDROXIDES
  • FREE-RADICALS
  • TRANSITION-METAL
  • EXCITED-STATES
  • X TRANSITIONS
  • CAOH
  • FLUORESCENCE
  • MOLECULES

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