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h(1)-2-pyrone metal carbonyl complexes as CO-releasing molecules (CO-RMs): A delicate balance between stability and CO liberation

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Publication details

JournalDalton Transactions
DatePublished - 2007
Issue number33
Number of pages3
Pages (from-to)3603-3605
Original languageEnglish

Abstract

An evaluation of the CO releasing ability of iron(II) and molybdenum( II) complexes has facilitated the discovery of the most rapid CO releaser, namely [Mo( CO) 3(eta(5)-C5H5)(eta(1)-{O} C{= O}-O-CMe=CH-COMe=CBr)]BF4 (CORM-F10), reported to date. The rate of CO release is related to the overall solution phase stability of the transition metal carbonyl complex. The cytotoxity and vasodilatory properties of CORM-F10 have been determined.

    Research areas

  • HEME OXYGENASE-1, IN-VIVO, MONOXIDE, PHARMACEUTICALS, CHEMISTRY, PATHWAY, IRON

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