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h(1)-2-pyrone metal carbonyl complexes as CO-releasing molecules (CO-RMs): A delicate balance between stability and CO liberation
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| Journal | Dalton Transactions |
|---|---|
| Date | Published - 2007 |
| Issue number | 33 |
| Number of pages | 3 |
| Pages (from-to) | 3603-3605 |
| Original language | English |
Abstract
An evaluation of the CO releasing ability of iron(II) and molybdenum( II) complexes has facilitated the discovery of the most rapid CO releaser, namely [Mo( CO) 3(eta(5)-C5H5)(eta(1)-{O} C{= O}-O-CMe=CH-COMe=CBr)]BF4 (CORM-F10), reported to date. The rate of CO release is related to the overall solution phase stability of the transition metal carbonyl complex. The cytotoxity and vasodilatory properties of CORM-F10 have been determined.
- HEME OXYGENASE-1, IN-VIVO, MONOXIDE, PHARMACEUTICALS, CHEMISTRY, PATHWAY, IRON
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