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Halide and pseudohalide effects in Pd-catalysed cross-coupling reactions

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JournalNEW JOURNAL OF CHEMISTRY
DatePublished - Dec 2006
Issue number12
Volume30
Number of pages10
Pages (from-to)1695-1704
Original languageEnglish

Abstract

The presence of halide and pseudohalide anions dramatically affects the outcome of transition-metal catalysed reactions, both in terms of selectivity and activity. In this perspective, the roles and effects of these anionic ligands in topical and important Pd-catalysed cross-coupling reactions involving the formation of C-C bonds, e.g. Sonogashira, Stille and Suzuki-Miyaura cross-coupling, will be described. The use of imidate anions (derived from succinimide, maleimide and phthalimide) in several different classes of neutral and anionic Pd catalysts/precatalysts will be highlighted.

    Research areas

  • ZEROVALENT PALLADIUM COMPLEXES, MU-HYDROXO COMPLEX, C-H BONDS, HECK REACTION, OXIDATIVE ADDITION, ARYL BROMIDES, PALLADACYCLOPENTADIENE COMPLEXES, METATHESIS REACTIONS, IMIDATE LIGANDS, STILLE REACTION

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