Heterobimetallic lithium alkyltriimido aluminate cages containing the [R ' Al(NR)(3)](4-) tetraanion (R ' = Bu-n, Et; R=2-OMeC6H4)

M C  Copsey; J C  Jeffery; C A  Russell; J M  Slattery; J A  Straughan

doi:10.1039/b307589c

Heterobimetallic lithium alkyltriimido aluminate cages containing the [R ' Al(NR)(3)](4-) tetraanion (R ' = Bu-n, Et; R=2-OMeC6H4)

M C Copsey, J C Jeffery, C A Russell, J M Slattery, J A Straughan

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Attempted metallation of a triamidoaluminane gives a complex containing the [R'Al(NR)(3)](4-) anion whose formal tetranegative charge is the highest charge observed crystallographically for a simple mononuclear imido main group anion system.

Original language	English
Pages (from-to)	2356-2357
Number of pages	2
Journal	Chemical Communications
Volume	18
DOIs	https://doi.org/10.1039/b307589c
Publication status	Published - 21 Sept 2003

Keywords

X-RAY STRUCTURES
IMIDO ANALOGS
BUTYLLITHIUM
PHOSPHORUS
OXOANIONS
COMPLEXES
ANION

Access to Document

10.1039/b307589c

http://dx.doi.org/10.1039/b307589c

Cite this

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title = "Heterobimetallic lithium alkyltriimido aluminate cages containing the [R ' Al(NR)(3)](4-) tetraanion (R ' = Bu-n, Et; R=2-OMeC6H4)",

abstract = "Attempted metallation of a triamidoaluminane gives a complex containing the [R'Al(NR)(3)](4-) anion whose formal tetranegative charge is the highest charge observed crystallographically for a simple mononuclear imido main group anion system.",

keywords = "X-RAY STRUCTURES, IMIDO ANALOGS, BUTYLLITHIUM, PHOSPHORUS, OXOANIONS, COMPLEXES, ANION",

author = "Copsey, {M C} and Jeffery, {J C} and Russell, {C A} and Slattery, {J M} and Straughan, {J A}",

year = "2003",

month = sep,

day = "21",

doi = "10.1039/b307589c",

language = "English",

volume = "18",

pages = "2356--2357",

journal = "Chemical Communications",

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publisher = "The Royal Society of Chemistry",

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T1 - Heterobimetallic lithium alkyltriimido aluminate cages containing the [R ' Al(NR)(3)](4-) tetraanion (R ' = Bu-n, Et; R=2-OMeC6H4)

AU - Copsey, M C

AU - Jeffery, J C

AU - Russell, C A

AU - Slattery, J M

AU - Straughan, J A

PY - 2003/9/21

Y1 - 2003/9/21

N2 - Attempted metallation of a triamidoaluminane gives a complex containing the [R'Al(NR)(3)](4-) anion whose formal tetranegative charge is the highest charge observed crystallographically for a simple mononuclear imido main group anion system.

AB - Attempted metallation of a triamidoaluminane gives a complex containing the [R'Al(NR)(3)](4-) anion whose formal tetranegative charge is the highest charge observed crystallographically for a simple mononuclear imido main group anion system.

KW - X-RAY STRUCTURES

KW - IMIDO ANALOGS

KW - BUTYLLITHIUM

KW - PHOSPHORUS

KW - OXOANIONS

KW - COMPLEXES

KW - ANION

U2 - 10.1039/b307589c

DO - 10.1039/b307589c

M3 - Article

SN - 1359-7345

VL - 18

SP - 2356

EP - 2357

JO - Chemical Communications

JF - Chemical Communications

ER -