High-resolution Fourier-transform emission spectroscopy of the A(1)Pi-X(1)Sigma(AlH)-Al-+

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Abstract

The emission spectrum of the A(1) Pi-X(1) Sigma(+) system of AlH, excited in a hollow-cathode discharge lamp, has been observed at high resolution with a Fourier-transform spectrometer. The rotational lines in the 0-0 and the 1-1 bands have been measured with a precision of +/-0.001 cm(-1). The present measurements provide a considerable improvement over the previous data of Zeeman and Ritter [Can. J. Phys. 32, 555 (1954)]. The present data, combined with the previous high-resolution measurements of the 1-0 vibration-rotation band by White et al. [J. Chem. Phys. 99, 8371 (1993)] and the J = 1-0 pure rotational line of Goto and Saito [Astrophys. J. 452, L147 (1995)] have been used to determine improved constants for the A(1) Pi state. (C) 1996 Optical Society of America

Original languageEnglish
Pages (from-to)2879-2883
Number of pages5
JournalApplied Optics
Volume35
Issue number16
Publication statusPublished - 1 Jun 1996

Keywords

  • ISOLATED ALUMINUM ATOMS
  • PHOTOCHEMICAL-REACTIONS
  • ELECTRIC PROPERTIES
  • LASER SPECTROSCOPY
  • MOLECULAR-HYDROGEN
  • POTENTIAL CURVES
  • INFRARED-SPECTRA
  • ALH
  • STATE
  • AIH

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