High-resolution Fourier transform spectroscopy of three near-infrared transitions of NiF

B  Pinchemel; T  Hirao; P F  Bernath

doi:10.1006/jmsp.2002.8643

High-resolution Fourier transform spectroscopy of three near-infrared transitions of NiF

B Pinchemel, T Hirao, P F Bernath

Chemistry

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Abstract

The emission spectrum of the NiF radical has been recorded by high-resolution Fourier transform spectroscopy in the region 6000-12 000 cm(-1). Numerous new near-infrared bands were observed. In this paper three electronic transitions are analyzed leading to the identification of two new electronic states: a [12.0](2)Phi(7/2) state and a [11.1](2)Pi(3/2) state located, respectively, at 12 008.89 and 11096.05 cm(-1) above the X(2)Pi(3/2) ground state. These electronic states can be correlated to the [3d(8)(F-3)4s](2) F atomic term of Ni+ as predicted by Carette et al. [J. Mol. Spectrosc. 161, 323-335 (1993)]. (C) 2002 Elsevier Science (USA).

Original language	English
Pages (from-to)	262-268
Number of pages	7
Journal	JOURNAL OF MOLECULAR SPECTROSCOPY
Volume	215
Issue number	2
DOIs	https://doi.org/10.1006/jmsp.2002.8643
Publication status	Published - Oct 2002

Keywords

FLUORESCENCE
SPECTRUM

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10.1006/jmsp.2002.8643

Cite this

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title = "High-resolution Fourier transform spectroscopy of three near-infrared transitions of NiF",

abstract = "The emission spectrum of the NiF radical has been recorded by high-resolution Fourier transform spectroscopy in the region 6000-12 000 cm(-1). Numerous new near-infrared bands were observed. In this paper three electronic transitions are analyzed leading to the identification of two new electronic states: a [12.0](2)Phi(7/2) state and a [11.1](2)Pi(3/2) state located, respectively, at 12 008.89 and 11096.05 cm(-1) above the X(2)Pi(3/2) ground state. These electronic states can be correlated to the [3d(8)(F-3)4s](2) F atomic term of Ni+ as predicted by Carette et al. [J. Mol. Spectrosc. 161, 323-335 (1993)]. (C) 2002 Elsevier Science (USA).",

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author = "B Pinchemel and T Hirao and Bernath, {P F}",

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TY - JOUR

T1 - High-resolution Fourier transform spectroscopy of three near-infrared transitions of NiF

AU - Pinchemel, B

AU - Hirao, T

AU - Bernath, P F

PY - 2002/10

Y1 - 2002/10

N2 - The emission spectrum of the NiF radical has been recorded by high-resolution Fourier transform spectroscopy in the region 6000-12 000 cm(-1). Numerous new near-infrared bands were observed. In this paper three electronic transitions are analyzed leading to the identification of two new electronic states: a [12.0](2)Phi(7/2) state and a [11.1](2)Pi(3/2) state located, respectively, at 12 008.89 and 11096.05 cm(-1) above the X(2)Pi(3/2) ground state. These electronic states can be correlated to the [3d(8)(F-3)4s](2) F atomic term of Ni+ as predicted by Carette et al. [J. Mol. Spectrosc. 161, 323-335 (1993)]. (C) 2002 Elsevier Science (USA).

AB - The emission spectrum of the NiF radical has been recorded by high-resolution Fourier transform spectroscopy in the region 6000-12 000 cm(-1). Numerous new near-infrared bands were observed. In this paper three electronic transitions are analyzed leading to the identification of two new electronic states: a [12.0](2)Phi(7/2) state and a [11.1](2)Pi(3/2) state located, respectively, at 12 008.89 and 11096.05 cm(-1) above the X(2)Pi(3/2) ground state. These electronic states can be correlated to the [3d(8)(F-3)4s](2) F atomic term of Ni+ as predicted by Carette et al. [J. Mol. Spectrosc. 161, 323-335 (1993)]. (C) 2002 Elsevier Science (USA).

KW - FLUORESCENCE

KW - SPECTRUM

U2 - 10.1006/jmsp.2002.8643

DO - 10.1006/jmsp.2002.8643

M3 - Article

SN - 0022-2852

VL - 215

SP - 262

EP - 268

JO - JOURNAL OF MOLECULAR SPECTROSCOPY

JF - JOURNAL OF MOLECULAR SPECTROSCOPY

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