High-resolution survey of the visible spectrum of NiF by Fourier transform spectroscopy

Y  Krouti; T  Hirao; C  Dufour; A  Boulezhar; B  Pinchemel; P F  Bernath

doi:10.1006/jmsp.2002.8567

High-resolution survey of the visible spectrum of NiF by Fourier transform spectroscopy

Y Krouti, T Hirao, C Dufour, A Boulezhar, B Pinchemel, P F Bernath

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

High-resolution spectra of NiF have been recorded in emission by Fourier transform spectroscopy using a very stable discharge source. The 0-0 bands of 14 electronic transitions have been studied, 6 of them for the first time. This work confirms the presence of 5 low-lying spin components X(2)Pi(3/2), [0.25](2)Sigma(+), [0.83]A(2)Delta(5/2), [1.5]B(2)Sigma(+), and [2.2] A(2)Delta(3/2) as known from previous laser-induced fluorescence experiments. Eight electronic states are now identified in the 18 000-24 000 cm(-1) range above the ground X(2)Pi(3/2) state. Electronic assignments for these excited states are not always obvious because of violations of the selection rules and unusual fine structure parameters. We think that some of the upper states are spin components of quartet states. In such a congested spectrum, high-resolution spectra are best analyzed in conjunction with an energy level diagram constructed mainly by dispersed low resolution laser-induced fluorescence. (C) 2002 Elsevier Science (USA).

Original language	English
Pages (from-to)	152-174
Number of pages	23
Journal	JOURNAL OF MOLECULAR SPECTROSCOPY
Volume	214
Issue number	2
DOIs	https://doi.org/10.1006/jmsp.2002.8567
Publication status	Published - Aug 2002

Keywords

LASER-INDUCED FLUORESCENCE
TRANSITIONS
IDENTIFICATION
STATES
CM(-1)
NICL
REGION

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10.1006/jmsp.2002.8567

Cite this

@article{856f95a56ee74ae1aefc4045b4281ea4,

title = "High-resolution survey of the visible spectrum of NiF by Fourier transform spectroscopy",

abstract = "High-resolution spectra of NiF have been recorded in emission by Fourier transform spectroscopy using a very stable discharge source. The 0-0 bands of 14 electronic transitions have been studied, 6 of them for the first time. This work confirms the presence of 5 low-lying spin components X(2)Pi(3/2), [0.25](2)Sigma(+), [0.83]A(2)Delta(5/2), [1.5]B(2)Sigma(+), and [2.2] A(2)Delta(3/2) as known from previous laser-induced fluorescence experiments. Eight electronic states are now identified in the 18 000-24 000 cm(-1) range above the ground X(2)Pi(3/2) state. Electronic assignments for these excited states are not always obvious because of violations of the selection rules and unusual fine structure parameters. We think that some of the upper states are spin components of quartet states. In such a congested spectrum, high-resolution spectra are best analyzed in conjunction with an energy level diagram constructed mainly by dispersed low resolution laser-induced fluorescence. (C) 2002 Elsevier Science (USA).",

keywords = "LASER-INDUCED FLUORESCENCE, TRANSITIONS, IDENTIFICATION, STATES, CM(-1), NICL, REGION",

author = "Y Krouti and T Hirao and C Dufour and A Boulezhar and B Pinchemel and Bernath, {P F}",

year = "2002",

month = aug,

doi = "10.1006/jmsp.2002.8567",

language = "English",

volume = "214",

pages = "152--174",

journal = "JOURNAL OF MOLECULAR SPECTROSCOPY",

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publisher = "Academic Press",

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T1 - High-resolution survey of the visible spectrum of NiF by Fourier transform spectroscopy

AU - Krouti, Y

AU - Hirao, T

AU - Dufour, C

AU - Boulezhar, A

AU - Pinchemel, B

AU - Bernath, P F

PY - 2002/8

Y1 - 2002/8

N2 - High-resolution spectra of NiF have been recorded in emission by Fourier transform spectroscopy using a very stable discharge source. The 0-0 bands of 14 electronic transitions have been studied, 6 of them for the first time. This work confirms the presence of 5 low-lying spin components X(2)Pi(3/2), [0.25](2)Sigma(+), [0.83]A(2)Delta(5/2), [1.5]B(2)Sigma(+), and [2.2] A(2)Delta(3/2) as known from previous laser-induced fluorescence experiments. Eight electronic states are now identified in the 18 000-24 000 cm(-1) range above the ground X(2)Pi(3/2) state. Electronic assignments for these excited states are not always obvious because of violations of the selection rules and unusual fine structure parameters. We think that some of the upper states are spin components of quartet states. In such a congested spectrum, high-resolution spectra are best analyzed in conjunction with an energy level diagram constructed mainly by dispersed low resolution laser-induced fluorescence. (C) 2002 Elsevier Science (USA).

AB - High-resolution spectra of NiF have been recorded in emission by Fourier transform spectroscopy using a very stable discharge source. The 0-0 bands of 14 electronic transitions have been studied, 6 of them for the first time. This work confirms the presence of 5 low-lying spin components X(2)Pi(3/2), [0.25](2)Sigma(+), [0.83]A(2)Delta(5/2), [1.5]B(2)Sigma(+), and [2.2] A(2)Delta(3/2) as known from previous laser-induced fluorescence experiments. Eight electronic states are now identified in the 18 000-24 000 cm(-1) range above the ground X(2)Pi(3/2) state. Electronic assignments for these excited states are not always obvious because of violations of the selection rules and unusual fine structure parameters. We think that some of the upper states are spin components of quartet states. In such a congested spectrum, high-resolution spectra are best analyzed in conjunction with an energy level diagram constructed mainly by dispersed low resolution laser-induced fluorescence. (C) 2002 Elsevier Science (USA).

KW - LASER-INDUCED FLUORESCENCE

KW - TRANSITIONS

KW - IDENTIFICATION

KW - STATES

KW - CM(-1)

KW - NICL

KW - REGION

U2 - 10.1006/jmsp.2002.8567

DO - 10.1006/jmsp.2002.8567

M3 - Article

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VL - 214

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JO - JOURNAL OF MOLECULAR SPECTROSCOPY

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