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Homogeneous and silica-supported zinc complexes for the synthesis of propylene carbonate from propane-1,2-diol and carbon dioxide

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JournalCatalysis Science and Technology
DateAccepted/In press - 22 Feb 2016
DatePublished (current) - 23 Feb 2016
Issue number13
Volume6
Number of pages8
Pages (from-to)4824-4831
Original languageEnglish

Abstract

Three organozinc complexes have been synthesised and found to catalyse the carbonylation of propylene glycol with carbon dioxide to form propylene carbonate. A similar tethered organozinc complex was supported onto high loading aminopropyl functionalised hexagonal mesoporous silica and was also found to be catalytically active.

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© The Royal Society of Chemistry 2016. This is an author-produced version of the published paper. Uploaded in accordance with the publisher’s self-archiving policy. Further copying may not be permitted; contact the publisher for details

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