How to predict the physical properties of ionic liquids: A volume-based approach

John M. Slattery; Corinne Daguenet; Paul J. Dyson; Thomas J. S. Schubert; Ingo Krossing

doi:10.1002/anie.200700941

How to predict the physical properties of ionic liquids: A volume-based approach

John M. Slattery, Corinne Daguenet, Paul J. Dyson, Thomas J. S. Schubert, Ingo Krossing

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The molecular volume Vm (that is, the sum of the ionic volumes Vion of the constituent ions) of an ionic liquid (IL) in combination with an anion-dependent empirical relationship is all one needs to predict physical properties such as viscosity, conductivity, and density of [N(CN)2]-, [BF4]-, [PF6]-, and [N(SO2CF3)2]- ionic liquids, including those which may as yet only exist on paper.

Original language	English
Pages (from-to)	5384-5388
Number of pages	5
Journal	Angewandte Chemie International Edition
Volume	46
Issue number	28
DOIs	https://doi.org/10.1002/anie.200700941
Publication status	Published - 14 Jun 2007

Keywords

ionic liquids
molecular volumes
physical properties
predictive methods
sustainable chemistry
SENSITIZED SOLAR-CELLS
ROOM-TEMPERATURE
MELTING-POINTS
TRANSPORT-PROPERTIES
WATER
NANOPARTICLES
DENSITIES
ELECTROLYTES
EFFICIENCY
ENERGIES

Access to Document

10.1002/anie.200700941

http://dx.doi.org/10.1002/anie.200700941

Workshop on recent advances in theoretical approaches to ionic liquids (a satellite meeting to COIL-3)
Slattery, J. M. (Invited speaker)
31 May 2009
Activity: Participating in or organising an event › Conference participation
2nd International congress on ionic liquids (COIL-2)
Slattery, J. M. (Invited speaker)
5 Aug 2007 → 10 Aug 2007
Activity: Participating in or organising an event › Conference participation

Cite this

@article{f96c76d4a6f8472fb0bec2bb60859d65,

title = "How to predict the physical properties of ionic liquids: A volume-based approach",

abstract = "The molecular volume Vm (that is, the sum of the ionic volumes Vion of the constituent ions) of an ionic liquid (IL) in combination with an anion-dependent empirical relationship is all one needs to predict physical properties such as viscosity, conductivity, and density of [N(CN)2]-, [BF4]-, [PF6]-, and [N(SO2CF3)2]- ionic liquids, including those which may as yet only exist on paper.",

keywords = "ionic liquids, molecular volumes, physical properties, predictive methods, sustainable chemistry, SENSITIZED SOLAR-CELLS, ROOM-TEMPERATURE, MELTING-POINTS, TRANSPORT-PROPERTIES, WATER, NANOPARTICLES, DENSITIES, ELECTROLYTES, EFFICIENCY, ENERGIES",

author = "Slattery, {John M.} and Corinne Daguenet and Dyson, {Paul J.} and Schubert, {Thomas J. S.} and Ingo Krossing",

year = "2007",

month = jun,

day = "14",

doi = "10.1002/anie.200700941",

language = "English",

volume = "46",

pages = "5384--5388",

journal = "Angewandte Chemie International Edition",

issn = "1433-7851",

publisher = "Wiley-Blackwell",

number = "28",

}

TY - JOUR

T1 - How to predict the physical properties of ionic liquids: A volume-based approach

AU - Slattery, John M.

AU - Daguenet, Corinne

AU - Dyson, Paul J.

AU - Schubert, Thomas J. S.

AU - Krossing, Ingo

PY - 2007/6/14

Y1 - 2007/6/14

N2 - The molecular volume Vm (that is, the sum of the ionic volumes Vion of the constituent ions) of an ionic liquid (IL) in combination with an anion-dependent empirical relationship is all one needs to predict physical properties such as viscosity, conductivity, and density of [N(CN)2]-, [BF4]-, [PF6]-, and [N(SO2CF3)2]- ionic liquids, including those which may as yet only exist on paper.

AB - The molecular volume Vm (that is, the sum of the ionic volumes Vion of the constituent ions) of an ionic liquid (IL) in combination with an anion-dependent empirical relationship is all one needs to predict physical properties such as viscosity, conductivity, and density of [N(CN)2]-, [BF4]-, [PF6]-, and [N(SO2CF3)2]- ionic liquids, including those which may as yet only exist on paper.

KW - ionic liquids

KW - molecular volumes

KW - physical properties

KW - predictive methods

KW - sustainable chemistry

KW - SENSITIZED SOLAR-CELLS

KW - ROOM-TEMPERATURE

KW - MELTING-POINTS

KW - TRANSPORT-PROPERTIES

KW - WATER

KW - NANOPARTICLES

KW - DENSITIES

KW - ELECTROLYTES

KW - EFFICIENCY

KW - ENERGIES

U2 - 10.1002/anie.200700941

DO - 10.1002/anie.200700941

M3 - Article

SN - 1433-7851

VL - 46

SP - 5384

EP - 5388

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

IS - 28

ER -

How to predict the physical properties of ionic liquids: A volume-based approach

Abstract

Keywords

Access to Document

Activities

Workshop on recent advances in theoretical approaches to ionic liquids (a satellite meeting to COIL-3)

2nd International congress on ionic liquids (COIL-2)

Cite this