Hydroacenes Made Easy by Gold(I) Catalysis

Ruth Dorel; Paul R. McGonigal; Antonio M. Echavarren

doi:10.1002/anie.201604952

Hydroacenes Made Easy by Gold(I) Catalysis

Ruth Dorel, Paul R. McGonigal, Antonio M. Echavarren^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A novel strategy for the synthesis of partially saturated acene derivatives has been developed based on a Au^I-catalyzed cyclization of 1,7-enynes. This method provides straightforward access to stable polycyclic products featuring the backbone of the acene series, up to nonacene.

Original language	English
Pages (from-to)	11120-11123
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	55
Issue number	37
DOIs	https://doi.org/10.1002/anie.201604952
Publication status	Published - 5 Sept 2016

Bibliographical note

Funding Information:
We thank MINECO (Severo Ochoa Excellence Accreditation 2014–2018 (SEV-2013-0319), project CTQ2013-42106-P), the European Research Council (Advanced Grant No. 321066), the AGAUR (2014 SGR 818), and the ICIQ Foundation. We also thank the research support area of ICIQ.

Publisher Copyright:
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

Keywords

1,7-enynes
acenes
cycloaddition
gold(I) catalysis
Sonogashira coupling

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10.1002/anie.201604952

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title = "Hydroacenes Made Easy by Gold(I) Catalysis",

abstract = "A novel strategy for the synthesis of partially saturated acene derivatives has been developed based on a AuI-catalyzed cyclization of 1,7-enynes. This method provides straightforward access to stable polycyclic products featuring the backbone of the acene series, up to nonacene.",

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author = "Ruth Dorel and McGonigal, {Paul R.} and Echavarren, {Antonio M.}",

note = "Funding Information: We thank MINECO (Severo Ochoa Excellence Accreditation 2014–2018 (SEV-2013-0319), project CTQ2013-42106-P), the European Research Council (Advanced Grant No. 321066), the AGAUR (2014 SGR 818), and the ICIQ Foundation. We also thank the research support area of ICIQ. Publisher Copyright: {\textcopyright} 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",

year = "2016",

month = sep,

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doi = "10.1002/anie.201604952",

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AU - Dorel, Ruth

AU - McGonigal, Paul R.

AU - Echavarren, Antonio M.

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PY - 2016/9/5

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N2 - A novel strategy for the synthesis of partially saturated acene derivatives has been developed based on a AuI-catalyzed cyclization of 1,7-enynes. This method provides straightforward access to stable polycyclic products featuring the backbone of the acene series, up to nonacene.

AB - A novel strategy for the synthesis of partially saturated acene derivatives has been developed based on a AuI-catalyzed cyclization of 1,7-enynes. This method provides straightforward access to stable polycyclic products featuring the backbone of the acene series, up to nonacene.

KW - 1,7-enynes

KW - acenes

KW - cycloaddition

KW - gold(I) catalysis

KW - Sonogashira coupling

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M3 - Article

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 37

ER -

Hydroacenes Made Easy by Gold(I) Catalysis

Abstract

Bibliographical note

Keywords

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