Hydrophilicity, the major determining factor influencing the solvation environment of protic ionic liquids

TY - JOUR

T1 - Hydrophilicity, the major determining factor influencing the solvation environment of protic ionic liquids

AU - Wright, Lawrence

AU - Sanders, Marc W.

AU - Tate, Lauren

AU - Fairless, Gayle

AU - Crowhurst, Lorna

AU - Bruce, Neil C.

AU - Walker, Adam J.

AU - Hembury, Guy A.

AU - Shimizu, Seishi

PY - 2010/8/21

Y1 - 2010/8/21

N2 - The study of solubility of 4-nitroaniline and its N,N-diethyl derivative in ionic liquids (ILs) of varying water content has shown that it is the interaction between water and the ILs' ions, and not with the solute, that is the most important factor determining the solute's preferential hydration parameter and thus the solvation shell structure.

AB - The study of solubility of 4-nitroaniline and its N,N-diethyl derivative in ionic liquids (ILs) of varying water content has shown that it is the interaction between water and the ILs' ions, and not with the solute, that is the most important factor determining the solute's preferential hydration parameter and thus the solvation shell structure.

KW - PREFERENTIAL INTERACTION COEFFICIENTS

KW - HYDRATION

KW - TEMPERATURE

KW - ETHANOL

KW - MODEL

UR - http://www.scopus.com/inward/record.url?scp=77955107086&partnerID=8YFLogxK

U2 - 10.1039/b919348k

DO - 10.1039/b919348k

M3 - Article

SN - 1463-9076

VL - 12

SP - 9063

EP - 9066

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

IS - 31

ER -