Imaging and Characterization of Engineered Nanoparticles in Sunscreens by Electron Microscopy, Under Wet and Dry Conditions

Christiane Lorenz, Karen Tiede, Steven Tear, Alistair Boxall, Natalie von Goetz, Konrad Hungerbuehler

Research output: Contribution to journalArticlepeer-review

Abstract

There is increasing concern over the risks of nanopartidies to humans and the environment, but little is known about the properties of the nanoparticulate mineral filters, such as titanium dioxide and zinc oxide, in sunscreens. There is an urgent need to develop methods for characterizing nanoparticles in (NPs) such products to provide data for human and environmental risk assessments. This study explored three methods (transmission electron microscopy [TEM], conventional scanning electron microscopy [SEM], and wet-scanning electron microscopy [WetSEM]) for characterizing NPs in sunscreens. Our results showed that these products contained titanium dioxide and zinc oxide particles in the nanometer range; thus, it is likely that consumers and the environment are exposed to engineered NPs through the use of these products. Further, we found that the combination of all three microscopy methods provided the most comprehensive information on size-related properties, which are crucial parameters for risk assessment of NPs in wet matrices.

Original languageEnglish
Pages (from-to)406-428
Number of pages23
JournalInternational journal of occupational and environmental health
Volume16
Issue number4
Publication statusPublished - 2010

Keywords

  • sunscreen
  • mineral filters
  • electron microscopy
  • WetSEM
  • wet imaging
  • titanium dioxide
  • zinc oxide
  • nanomaterials
  • TEM
  • SEM
  • engineered nanoparticles (ENPs)
  • UV FILTERS
  • ION MICROSCOPY
  • SKIN
  • EXPOSURE
  • ECOTOXICITY
  • PENETRATION
  • ENVIRONMENT
  • PRODUCTS
  • RISK

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