Improved on-line benchtop 31P NMR reaction monitoring via multi resonance SHARPER

Laura Tadiello; Meghan Eileen Halse; Torsten Beweries

doi:10.1039/D4AY00948G

Improved on-line benchtop 31P NMR reaction monitoring via multi resonance SHARPER

Laura Tadiello, Meghan Eileen Halse, Torsten Beweries^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

On-line reaction monitoring of hydrogenation reactions featuring oxygen-sensitive organometallic complexes are followed via a 31P benchtop NMR spectrometer with Multi-Resonance Sensitive Homogeneous And Resolved PEaks in Real time (MR-SHARPER) sequence. Signal enhacement generated by MR-SHARPER enables monitoring of reactivity on the order of minutes that could not be followed with traditional 31P{1H} NMR detection.

Original language	English
Journal	Analytical methods
DOIs	https://doi.org/10.1039/D4AY00948G
Publication status	Accepted/In press - 12 Jul 2024

Access to Document

10.1039/D4AY00948GLicence: CC BY

Hyperpolarised portable NMR for targeted analytical solutions beyond the laboratory (HYPERSOL)
Halse, M. E. (Principal investigator)
EUROPEAN COMMISSION
1/01/23 → 31/12/27
Project: Research project (funded) › Research

Cite this

@article{4eed48a83cc54811a21c9602e120cda2,

title = "Improved on-line benchtop 31P NMR reaction monitoring via multi resonance SHARPER",

abstract = "On-line reaction monitoring of hydrogenation reactions featuring oxygen-sensitive organometallic complexes are followed via a 31P benchtop NMR spectrometer with Multi-Resonance Sensitive Homogeneous And Resolved PEaks in Real time (MR-SHARPER) sequence. Signal enhacement generated by MR-SHARPER enables monitoring of reactivity on the order of minutes that could not be followed with traditional 31P{1H} NMR detection.",

author = "Laura Tadiello and Halse, {Meghan Eileen} and Torsten Beweries",

year = "2024",

month = jul,

day = "12",

doi = "10.1039/D4AY00948G",

language = "English",

journal = "Analytical methods",

issn = "1759-9660",

publisher = "The Royal Society of Chemistry",

}

TY - JOUR

T1 - Improved on-line benchtop 31P NMR reaction monitoring via multi resonance SHARPER

AU - Tadiello, Laura

AU - Halse, Meghan Eileen

AU - Beweries, Torsten

PY - 2024/7/12

Y1 - 2024/7/12

N2 - On-line reaction monitoring of hydrogenation reactions featuring oxygen-sensitive organometallic complexes are followed via a 31P benchtop NMR spectrometer with Multi-Resonance Sensitive Homogeneous And Resolved PEaks in Real time (MR-SHARPER) sequence. Signal enhacement generated by MR-SHARPER enables monitoring of reactivity on the order of minutes that could not be followed with traditional 31P{1H} NMR detection.

AB - On-line reaction monitoring of hydrogenation reactions featuring oxygen-sensitive organometallic complexes are followed via a 31P benchtop NMR spectrometer with Multi-Resonance Sensitive Homogeneous And Resolved PEaks in Real time (MR-SHARPER) sequence. Signal enhacement generated by MR-SHARPER enables monitoring of reactivity on the order of minutes that could not be followed with traditional 31P{1H} NMR detection.

U2 - 10.1039/D4AY00948G

DO - 10.1039/D4AY00948G

M3 - Article

SN - 1759-9660

JO - Analytical methods

JF - Analytical methods

ER -

Improved on-line benchtop 31P NMR reaction monitoring via multi resonance SHARPER

Abstract

Access to Document

Projects

Hyperpolarised portable NMR for targeted analytical solutions beyond the laboratory (HYPERSOL)

Cite this