In situ alcohol oxidation-Wittig reactions using non-stabilised phosphoranes

L  Blackburn; C X  Pei; R J K  Taylor

In situ alcohol oxidation-Wittig reactions using non-stabilised phosphoranes

L Blackburn, C X Pei, R J K Taylor

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

New procedures have been developed which allow the in situ alcohol oxidation-Wittig reaction using manganese dioxide to be employed with non-stabilised phosphoranes and stabilised phosphonate anions. A number of examples are described utilising benzylic, allylic and propargylic alcohols.

Original language	English
Pages (from-to)	215-218
Number of pages	4
Journal	Synlett
Issue number	2
Publication status	Published - Feb 2002

Keywords

alkenes
Horner-Wadsworth-Emmons
oxidation
tandem
Wittig
EMMONS

Cite this

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title = "In situ alcohol oxidation-Wittig reactions using non-stabilised phosphoranes",

abstract = "New procedures have been developed which allow the in situ alcohol oxidation-Wittig reaction using manganese dioxide to be employed with non-stabilised phosphoranes and stabilised phosphonate anions. A number of examples are described utilising benzylic, allylic and propargylic alcohols.",

keywords = "alkenes, Horner-Wadsworth-Emmons, oxidation, tandem, Wittig, EMMONS",

author = "L Blackburn and Pei, {C X} and Taylor, {R J K}",

year = "2002",

month = feb,

language = "English",

pages = "215--218",

journal = "Synlett",

issn = "1437-2096",

publisher = "Georg Thieme Verlag",

number = "2",

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T1 - In situ alcohol oxidation-Wittig reactions using non-stabilised phosphoranes

AU - Blackburn, L

AU - Pei, C X

AU - Taylor, R J K

PY - 2002/2

Y1 - 2002/2

N2 - New procedures have been developed which allow the in situ alcohol oxidation-Wittig reaction using manganese dioxide to be employed with non-stabilised phosphoranes and stabilised phosphonate anions. A number of examples are described utilising benzylic, allylic and propargylic alcohols.

AB - New procedures have been developed which allow the in situ alcohol oxidation-Wittig reaction using manganese dioxide to be employed with non-stabilised phosphoranes and stabilised phosphonate anions. A number of examples are described utilising benzylic, allylic and propargylic alcohols.

KW - alkenes

KW - Horner-Wadsworth-Emmons

KW - oxidation

KW - tandem

KW - Wittig

KW - EMMONS

M3 - Article

SN - 1437-2096

SP - 215

EP - 218

JO - Synlett

JF - Synlett

IS - 2

ER -