Increasing Catalyst Efficiency in C−H Activation Catalysis

Tobias Gensch; Michael J. James; Toryn Dalton; Frank Glorius

doi:10.1002/anie.201710377

Increasing Catalyst Efficiency in C−H Activation Catalysis

Tobias Gensch, Michael J. James, Toryn Dalton, Frank Glorius^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Review article › peer-review

Abstract

C−H activation reactions with high catalyst turnover numbers are still very rare in the literature and 10 mol % is a common catalyst loading in this field. We offer a representative overview of efficient C−H activation catalysis to highlight this neglected aspect of catalysis development and inspire future effort towards more efficient C−H activation. Examples ranging from palladium catalysis, Cp*Rh ^III - and Cp*Co ^III -catalysis, the C−H borylation and silylation to methane C−H activation are presented. In these reactions, up to tens of thousands of catalyst turnovers have been observed.

Original language	English
Pages (from-to)	2296-2306
Number of pages	11
Journal	Angewandte Chemie - International Edition
Volume	57
Issue number	9
DOIs	https://doi.org/10.1002/anie.201710377
Publication status	Published - 23 Feb 2018

Bibliographical note

© 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim. This is an author-produced version of the published paper. Uploaded in accordance with the publisher’s self-archiving policy. Further copying may not be permitted; contact the publisher for details.

Keywords

catalysis
C−H activation
methane
palladium
rhodium
turnover

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10.1002/anie.201710377

Increasing Catalyst
© 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim. This is an author-produced version of the published paper. Uploaded in accordance with the publisher’s self-archiving policy. Further copying may not be permitted; contact the publisher for details.
Accepted author manuscript, 1.59 MB

Cite this

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title = "Increasing Catalyst Efficiency in C−H Activation Catalysis",

abstract = " C−H activation reactions with high catalyst turnover numbers are still very rare in the literature and 10 mol % is a common catalyst loading in this field. We offer a representative overview of efficient C−H activation catalysis to highlight this neglected aspect of catalysis development and inspire future effort towards more efficient C−H activation. Examples ranging from palladium catalysis, Cp*Rh III - and Cp*Co III -catalysis, the C−H borylation and silylation to methane C−H activation are presented. In these reactions, up to tens of thousands of catalyst turnovers have been observed. ",

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N2 - C−H activation reactions with high catalyst turnover numbers are still very rare in the literature and 10 mol % is a common catalyst loading in this field. We offer a representative overview of efficient C−H activation catalysis to highlight this neglected aspect of catalysis development and inspire future effort towards more efficient C−H activation. Examples ranging from palladium catalysis, Cp*Rh III - and Cp*Co III -catalysis, the C−H borylation and silylation to methane C−H activation are presented. In these reactions, up to tens of thousands of catalyst turnovers have been observed.

AB - C−H activation reactions with high catalyst turnover numbers are still very rare in the literature and 10 mol % is a common catalyst loading in this field. We offer a representative overview of efficient C−H activation catalysis to highlight this neglected aspect of catalysis development and inspire future effort towards more efficient C−H activation. Examples ranging from palladium catalysis, Cp*Rh III - and Cp*Co III -catalysis, the C−H borylation and silylation to methane C−H activation are presented. In these reactions, up to tens of thousands of catalyst turnovers have been observed.

KW - catalysis

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Increasing Catalyst Efficiency in C−H Activation Catalysis

Abstract

Bibliographical note

Keywords

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