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From the same journal

Influence of Mesoporous Silica Properties on Cyclic Carbonate Synthesis Catalysed by Supported Aluminium(Salen) Complexes

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Influence of Mesoporous Silica Properties on Cyclic Carbonate Synthesis Catalysed by Supported Aluminium(Salen) Complexes. / Carvalho, Patricia A.; Comerford, James W.; Lamb, Katie J.; North, Michael; Reiss, Paul S.

In: Advanced Synthesis and Catalysis, 01.11.2018, p. 1-11.

Research output: Contribution to journal › Article › peer-review

Harvard

Carvalho, PA, Comerford, JW, Lamb, KJ, North, M & Reiss, PS 2018, 'Influence of Mesoporous Silica Properties on Cyclic Carbonate Synthesis Catalysed by Supported Aluminium(Salen) Complexes', Advanced Synthesis and Catalysis, pp. 1-11. https://doi.org/10.1002/adsc.201801229

APA

Carvalho, P. A., Comerford, J. W., Lamb, K. J., North, M., & Reiss, P. S. (2018). Influence of Mesoporous Silica Properties on Cyclic Carbonate Synthesis Catalysed by Supported Aluminium(Salen) Complexes. Advanced Synthesis and Catalysis, 1-11. https://doi.org/10.1002/adsc.201801229

Vancouver

Carvalho PA, Comerford JW, Lamb KJ, North M, Reiss PS. Influence of Mesoporous Silica Properties on Cyclic Carbonate Synthesis Catalysed by Supported Aluminium(Salen) Complexes. Advanced Synthesis and Catalysis. 2018 Nov 1;1-11. https://doi.org/10.1002/adsc.201801229

Author

Carvalho, Patricia A. ; Comerford, James W. ; Lamb, Katie J. ; North, Michael ; Reiss, Paul S. / Influence of Mesoporous Silica Properties on Cyclic Carbonate Synthesis Catalysed by Supported Aluminium(Salen) Complexes. In: Advanced Synthesis and Catalysis. 2018 ; pp. 1-11.

Bibtex - Download

@article{605121fc38f944a6a54561abde6a5ab6,
title = "Influence of Mesoporous Silica Properties on Cyclic Carbonate Synthesis Catalysed by Supported Aluminium(Salen) Complexes",
abstract = "By modification of pore size and morphology, pore-expanded variants of SBA-15 and KIT-6 have been utilised as mesoporous silica supports for the immobilisation of a bimetallic aluminium-salen complex. The performance of the resulting heterogeneous catalysts in the synthesis of cyclic carbonates from carbon dioxide and terminal epoxides was assessed. Support materials which retained higher pore volume and surface areas after catalyst immobilisation demonstrated enhanced conversions to the desired cyclic carbonates. This was rationalised to be a consequence of the promotion of reactant mass transport through a less-inhibited pore structure. (Figure presented.).",
keywords = "Aluminium(salen), Carbon dioxide fixation, Cyclic carbonate, Epoxide, Heterogeneous catalysis, Mesoporous silica",
author = "Carvalho, {Patricia A.} and Comerford, {James W.} and Lamb, {Katie J.} and Michael North and Reiss, {Paul S.}",
note = "{\textcopyright} 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. This is an author-produced version of the published paper. Uploaded in accordance with the publisher{\textquoteright}s self-archiving policy. Further copying may not be permitted; contact the publisher for details. ",
year = "2018",
month = nov,
day = "1",
doi = "10.1002/adsc.201801229",
language = "English",
pages = "1--11",
journal = "Advanced Synthesis and Catalysis",
issn = "1615-4150",
publisher = "Wiley",

}

RIS (suitable for import to EndNote) - Download

TY - JOUR

T1 - Influence of Mesoporous Silica Properties on Cyclic Carbonate Synthesis Catalysed by Supported Aluminium(Salen) Complexes

AU - Carvalho, Patricia A.

AU - Comerford, James W.

AU - Lamb, Katie J.

AU - North, Michael

AU - Reiss, Paul S.

N1 - © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. This is an author-produced version of the published paper. Uploaded in accordance with the publisher’s self-archiving policy. Further copying may not be permitted; contact the publisher for details.

PY - 2018/11/1

Y1 - 2018/11/1

N2 - By modification of pore size and morphology, pore-expanded variants of SBA-15 and KIT-6 have been utilised as mesoporous silica supports for the immobilisation of a bimetallic aluminium-salen complex. The performance of the resulting heterogeneous catalysts in the synthesis of cyclic carbonates from carbon dioxide and terminal epoxides was assessed. Support materials which retained higher pore volume and surface areas after catalyst immobilisation demonstrated enhanced conversions to the desired cyclic carbonates. This was rationalised to be a consequence of the promotion of reactant mass transport through a less-inhibited pore structure. (Figure presented.).

AB - By modification of pore size and morphology, pore-expanded variants of SBA-15 and KIT-6 have been utilised as mesoporous silica supports for the immobilisation of a bimetallic aluminium-salen complex. The performance of the resulting heterogeneous catalysts in the synthesis of cyclic carbonates from carbon dioxide and terminal epoxides was assessed. Support materials which retained higher pore volume and surface areas after catalyst immobilisation demonstrated enhanced conversions to the desired cyclic carbonates. This was rationalised to be a consequence of the promotion of reactant mass transport through a less-inhibited pore structure. (Figure presented.).

KW - Aluminium(salen)

KW - Carbon dioxide fixation

KW - Cyclic carbonate

KW - Epoxide

KW - Heterogeneous catalysis

KW - Mesoporous silica

UR - http://www.scopus.com/inward/record.url?scp=85057304307&partnerID=8YFLogxK

U2 - 10.1002/adsc.201801229

DO - 10.1002/adsc.201801229

M3 - Article

AN - SCOPUS:85057304307

SP - 1

EP - 11

JO - Advanced Synthesis and Catalysis

JF - Advanced Synthesis and Catalysis

SN - 1615-4150

ER -

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