Infrared emission spectra of BeH2 and BeD2

A  Shayesteh; K  Tereszchuk; P F  Bernath; R  Colin

doi:10.1063/1.1539850

Infrared emission spectra of BeH2 and BeD2

A Shayesteh, K Tereszchuk, P F Bernath, R Colin

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

High resolution infrared emission spectra of beryllium dihydride and dideuteride have been recorded with a Fourier transform spectrometer. The molecules were generated in a discharge-furnace source, at 1500 degreesC and 333 mA discharge current, with beryllium metal and a mixture of helium and hydrogen or deuterium gases. The antisymmetric stretching modes (nu(3)) of BeH2 and BeD2, as well as several hot bands involving nu(1), nu(2), and nu(3), were rotationally analyzed and spectroscopic constants were determined. The equilibrium rotational constant (B-e) of BeH2 was found to be 4.753 66(2) cm-1, and the equilibrium bond distance (R-e) of 1.326 407(3) A was determined for BeH2. (C) 2003 American Institute of Physics.

Original language	English
Pages (from-to)	3622-3627
Number of pages	6
Journal	Journal of Chemical Physics
Volume	118
Issue number	8
DOIs	https://doi.org/10.1063/1.1539850
Publication status	Published - 22 Feb 2003

Keywords

BERYLLIUM HYDRIDE

Access to Document

10.1063/1.1539850

Cite this

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title = "Infrared emission spectra of BeH2 and BeD2",

abstract = "High resolution infrared emission spectra of beryllium dihydride and dideuteride have been recorded with a Fourier transform spectrometer. The molecules were generated in a discharge-furnace source, at 1500 degreesC and 333 mA discharge current, with beryllium metal and a mixture of helium and hydrogen or deuterium gases. The antisymmetric stretching modes (nu(3)) of BeH2 and BeD2, as well as several hot bands involving nu(1), nu(2), and nu(3), were rotationally analyzed and spectroscopic constants were determined. The equilibrium rotational constant (B-e) of BeH2 was found to be 4.753 66(2) cm-1, and the equilibrium bond distance (R-e) of 1.326 407(3) A was determined for BeH2. (C) 2003 American Institute of Physics.",

keywords = "BERYLLIUM HYDRIDE",

author = "A Shayesteh and K Tereszchuk and Bernath, {P F} and R Colin",

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language = "English",

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journal = "Journal of Chemical Physics",

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TY - JOUR

T1 - Infrared emission spectra of BeH2 and BeD2

AU - Shayesteh, A

AU - Tereszchuk, K

AU - Bernath, P F

AU - Colin, R

PY - 2003/2/22

Y1 - 2003/2/22

N2 - High resolution infrared emission spectra of beryllium dihydride and dideuteride have been recorded with a Fourier transform spectrometer. The molecules were generated in a discharge-furnace source, at 1500 degreesC and 333 mA discharge current, with beryllium metal and a mixture of helium and hydrogen or deuterium gases. The antisymmetric stretching modes (nu(3)) of BeH2 and BeD2, as well as several hot bands involving nu(1), nu(2), and nu(3), were rotationally analyzed and spectroscopic constants were determined. The equilibrium rotational constant (B-e) of BeH2 was found to be 4.753 66(2) cm-1, and the equilibrium bond distance (R-e) of 1.326 407(3) A was determined for BeH2. (C) 2003 American Institute of Physics.

AB - High resolution infrared emission spectra of beryllium dihydride and dideuteride have been recorded with a Fourier transform spectrometer. The molecules were generated in a discharge-furnace source, at 1500 degreesC and 333 mA discharge current, with beryllium metal and a mixture of helium and hydrogen or deuterium gases. The antisymmetric stretching modes (nu(3)) of BeH2 and BeD2, as well as several hot bands involving nu(1), nu(2), and nu(3), were rotationally analyzed and spectroscopic constants were determined. The equilibrium rotational constant (B-e) of BeH2 was found to be 4.753 66(2) cm-1, and the equilibrium bond distance (R-e) of 1.326 407(3) A was determined for BeH2. (C) 2003 American Institute of Physics.

KW - BERYLLIUM HYDRIDE

U2 - 10.1063/1.1539850

DO - 10.1063/1.1539850

M3 - Article

SN - 0021-9606

VL - 118

SP - 3622

EP - 3627

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 8

ER -